| 220381-79-3

• CAS: 220381-79-3
• 化学式: C₅₈H₇₂Cl₂N₂O₄Pt₂
• 分子量: 1322.29
• InChiKey: QOEDGDGVIKBFEB-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  potassium tetrachloroplatinate(II) 、 2,6-bis(4-hexyloxyphenyl)pyridine 以 溶剂黄146 为溶剂， 以63%的产率得到
  参考文献：
  名称：

  Inter- versus Intramolecular C−H Activation: Synthesis and Characterization of a Novel Platinum-Carbene Complex

  摘要：

  13 C NMR spectroscopy as well as the short bond between the platinum and the C4 atom of the pyridine ring in 1 (1.95 Å) indicate the formation of a novel carbene species. Compound 1 is remarkably stable (m.p. 246°C), probably due to the presence of intramolecular hydrogen bonds, and is formed instead of the expected cyclometalated product. R=n-hexyl.

  DOI：

  10.1002/(sici)1521-3773(19981217)37:23<3270::aid-anie3270>3.0.co;2-2