[Tl(2,2'-dimethyl-4,4'-dithiazole(-1))2(NO3)(DMSO)] | 1092575-96-6

• 英文名称: [Tl(2,2'-dimethyl-4,4'-dithiazole(-1))2(NO3)(DMSO)]
• CAS: 1092575-96-6
• 化学式: C₁₈H₂₀N₅O₄S₅Tl
• 分子量: 735.101
• InChiKey: IHZXRKSCXMLJRU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [Tl(2,2'-dimethyl-4,4'-dithiazole(-1))2(NO3)(H2O)] 、 二甲基亚砜 以 二甲基亚砜 为溶剂， 生成 [Tl(2,2'-dimethyl-4,4'-dithiazole(-1))2(NO3)(DMSO)]
  参考文献：
  名称：

  C–H activation in bithiazole ring with thallium(III) ion

  摘要：

  Two novel organometallic complex of 2,2'-dimethyl-4,4'-bithiazole (dm4bt) ligand (L) with formula [TI(dm4bt)(2)(NO(3))(H(2)O)] (1) and [TI(dm4bt)(2)(NO(3))(DMSO)] (2) have been synthesized and structurally characterized by elemental analysis, FT-IR, (1)H NMR spectra and X-ray crystallography. These complexes also display the first transoid conformation in bithiazole ligands in which C-H bond activation in bithiazole ring is observed with TI(III) ion. (C) 2008 Published by Elsevier B. V.

  DOI：

  10.1016/j.jorganchem.2008.08.027