[gadolinium(α-furancarboxylic acid)2(NO3)(2,2'-bipyridyl)]2 | 918428-86-1

• 英文名称: [gadolinium(α-furancarboxylic acid)2(NO3)(2,2'-bipyridyl)]2
• CAS: 918428-86-1
• 化学式: C₄₀H₂₈Gd₂N₆O₁₈
• 分子量: 1195.19
• InChiKey: GAPVROVCPJUFSS-UHFFFAOYSA-J

反应信息

• 作为产物：
  描述：

  糠酸（呋喃甲酸） 、 2,2'-联吡啶 、 gadolinium(III) nitrate hexahydrate 以 乙醇 、 水 为溶剂， 生成 [gadolinium(α-furancarboxylic acid)2(NO3)(2,2'-bipyridyl)]2
  参考文献：
  名称：

  Crystal and molecular structure of a new gadolinium nitrate complex with furancarboxylic acid and dipyridyl

  摘要：

  The gadolinium nitrato complex with alpha-furancarboxylic acid (FA) and 2,2'- dipyridyl (Dipy) has been synthesized. According to X-ray diffraction results, the complex is composed of the [Gd(FA)(2)(NO3)(Dipy)](2) dimers. The crystals are triclinic: a = 9.942(2) angstrom, b = 10.231( 2) angstrom, c = 11.037( 2) angstrom, alpha = 85.50( 3), beta = 75.71( 3), gamma = 69.82( 3), Z = 1. Two gadolinium atoms are linked by four carboxylate groups of furancarboxylic acid molecules. Each gadolinium atom is coordinated to seven oxygen atoms (five belonging to the FA carboxyl groups and two belonging to the bidentate nitrate group) and to two nitrogen atoms (from Dipy).

  DOI：

  10.1134/s0036023606030089