[diruthenium(η6-C6H5Me)(2,5-dihydroxy-1,4-benzoquinone-2H)Cl2] | 1185359-24-3

• 英文名称: [diruthenium(η6-C6H5Me)(2,5-dihydroxy-1,4-benzoquinone-2H)Cl2]
• 英文别名: [Ru2(η6-C6H5Me)2(dhbq)Cl2]
• CAS: 1185359-24-3
• 化学式: C₂₀H₁₈Cl₂O₄Ru₂
• 分子量: 595.407
• InChiKey: SFVCOYMPXDHJPJ-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  5,10,15,20-tetra(4-pyridyl)-21H,23H-porphine 、 silver trifluoromethanesulfonate 、 [diruthenium(η6-C6H5Me)(2,5-dihydroxy-1,4-benzoquinone-2H)Cl2] 以 二氯甲烷 为溶剂， 以83%的产率得到[Ru8(η-C6H5Me)8(5,10,15,20-tetra(4-pyridyl)porphyrin)2(2,5-dioxy-1,4-benzoquinone)4][CF3SO3]8
  参考文献：
  名称：

  Organometallic boxes built from 5,10,15,20-tetra(4-pyridyl)porphyrin panels and hydroxyquinonato-bridged diruthenium clips

  摘要：

  Self-assembly of 5,10,15,20-tetra(4-pyridyl)porphyrin (tpp-H-2) tetradentate panels with dinuclear arene ruthenium clips [Ru-2(eta(6)-arene)(2)(dhbq)Cl-2] (arene = C6H5Me, p-(PrC6H4Me)-C-i, C6Me6; dhbq = 2,5-dihydroxy-1,4-benzoquinonato) affords the cationic organometallic boxes [Ru-8(eta(6)-C6H5Me)(8)(tpp-H-2)(2)(dhbq)(4)](8+) ([1](8+)), [Ru-8(eta(6)-p-(PrC6H4Me)-C-i)(8)(tpp-H-2)(2)(dhbq)(4)](8+) ([2](8+)) and [Ru-8(eta(6)-C6Me6)(8)(tpp-H-2)(2)(dhbq)(4)](8+) ([3](8+)). These octanuclear cations have been isolated as their triflate salts and characterised by mass spectrometry, NMR and IR spectroscopy. The molecular structure of these systems was deduced by one-dimensional and two-dimensional NMR experiments (ROESY, COSY, HSQC). (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2008.08.007
• 作为产物：
  描述：

  bis[dichlorido(η6-toluene)ruthenium(II)] 、 2,5-二羟基-1,4-苯喹酮 以 甲醇 为溶剂， 以80%的产率得到[diruthenium(η6-C6H5Me)(2,5-dihydroxy-1,4-benzoquinone-2H)Cl2]
  参考文献：
  名称：

  Organometallic boxes built from 5,10,15,20-tetra(4-pyridyl)porphyrin panels and hydroxyquinonato-bridged diruthenium clips

  摘要：

  Self-assembly of 5,10,15,20-tetra(4-pyridyl)porphyrin (tpp-H-2) tetradentate panels with dinuclear arene ruthenium clips [Ru-2(eta(6)-arene)(2)(dhbq)Cl-2] (arene = C6H5Me, p-(PrC6H4Me)-C-i, C6Me6; dhbq = 2,5-dihydroxy-1,4-benzoquinonato) affords the cationic organometallic boxes [Ru-8(eta(6)-C6H5Me)(8)(tpp-H-2)(2)(dhbq)(4)](8+) ([1](8+)), [Ru-8(eta(6)-p-(PrC6H4Me)-C-i)(8)(tpp-H-2)(2)(dhbq)(4)](8+) ([2](8+)) and [Ru-8(eta(6)-C6Me6)(8)(tpp-H-2)(2)(dhbq)(4)](8+) ([3](8+)). These octanuclear cations have been isolated as their triflate salts and characterised by mass spectrometry, NMR and IR spectroscopy. The molecular structure of these systems was deduced by one-dimensional and two-dimensional NMR experiments (ROESY, COSY, HSQC). (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2008.08.007