{bis-(η5-tetramethylphospholyl)uranium borohydride} | 130168-05-7

• 英文名称: {bis-(η5-tetramethylphospholyl)uranium borohydride}
• CAS: 130168-05-7
• 化学式: C₁₆H₃₂B₂P₂U
• 分子量: 546.029
• InChiKey: WMOJXXONAKOHIN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  {bis-(η5-tetramethylphospholyl)uranium borohydride} 、 甲基锂 以 甲苯 为溶剂， 以76%的产率得到{dimethylbis-(η5-tetramethylphospholyl)uranium}
  参考文献：
  名称：

  Tetramethylphospholyluranium complexes and their pentamethylcyclopentadienyl analogues

  摘要：

  The mono- and bis-(tetramethylphospholyl)uranium complexes [U(tmp)(Cl)(3)(L)(2)] (tmp = C(4)Me(4)P, L = tetrahydrofuran or L(2) = dimethoxyethane), [U(tmp)(X)(3)] (X = BH4, CH(2)Ph) and [U(tmp)(2)(X)(2)] (X = Cl, BH4, alkyl, or alkoxide) were compared with their pentamethylcyclopentadienyl (cp*) analogues. The crystal structures of [U(tmp)(Cl)(3)(dimethoxyethane)] and [U(cp*)(2)(BH4)(2)] have been determined. Although the structures of the phospholyl compounds are similar to those of their cyclopentadienyl counterparts, the distinct electronic effects of the tmp and cp* ligands (tmp being less electron-donating than cp*) are manifest in the coordinating and redox properties of the complexes.

  DOI：

  10.1016/0022-328x(94)88035-2
• 作为产物：
  描述：

  {methyl-bis(η5-tetramethylphospholyl)uranium borohydride} 生成 {bis-(η5-tetramethylphospholyl)uranium borohydride}
  参考文献：
  名称：

  Tetramethylphospholyluranium complexes and their pentamethylcyclopentadienyl analogues

  摘要：

  The mono- and bis-(tetramethylphospholyl)uranium complexes [U(tmp)(Cl)(3)(L)(2)] (tmp = C(4)Me(4)P, L = tetrahydrofuran or L(2) = dimethoxyethane), [U(tmp)(X)(3)] (X = BH4, CH(2)Ph) and [U(tmp)(2)(X)(2)] (X = Cl, BH4, alkyl, or alkoxide) were compared with their pentamethylcyclopentadienyl (cp*) analogues. The crystal structures of [U(tmp)(Cl)(3)(dimethoxyethane)] and [U(cp*)(2)(BH4)(2)] have been determined. Although the structures of the phospholyl compounds are similar to those of their cyclopentadienyl counterparts, the distinct electronic effects of the tmp and cp* ligands (tmp being less electron-donating than cp*) are manifest in the coordinating and redox properties of the complexes.

  DOI：

  10.1016/0022-328x(94)88035-2

文献信息

• Synthesis of Phospholyl-Bridged Heterobimetallic Ruthenium Hydrides in Combination with Zirconium and Ytterbium and the Crystal Structure of (THF)₂Yb[μ(η⁵,η¹)-C₄Me₄P]₂Ru(H)₂(Ph₃P)₂
  作者：P. Desmurs、M. Visseaux、D. Baudry、A. Dormond、F. Nief、L. Ricard

  DOI：10.1021/om9602320

  日期：1996.10.1

  Heterobimetallic zirconium-ruthenium and ytterbium-ruthenium dihydrides, having bridging phospholyl ligands, have been obtained for the first time. Reaction of bin(eta(5)-tetramethylphospholyl)dichlorozirconium [(TMP)(2)ZrCl2] with RuH4(PPh(3))(3) gave the zirconium-ruthenium heterobimetallic Cl2Zr[mu(eta(5),eta(1))-TMP]Ru-2(H)(2)(PPh(3))(2). This compound was transformed into the hydridochloride Cl2Zr[mu(eta(5),eta(1))-TMP]Ru-2(H)(Cl)(PPh(3))(2) by the action of CCl4. Similarly, reaction of [(TMP)(2)Yb] with RuH4(PPh(3))(3) afforded (THF)(2)Yb[mu(eta(5),eta(1))-TMP]Ru-2(H)(2)(PPh(3))(2). The structure of this compound, which has been determined by X-ray crystallography, confirms the trans configuration of the dihydride deduced previously from NMR data. Attempts to isolate products from the reaction of [(TMP)(2)UCl2] or [(TMP)(2)U(BH4)(2)] with RuH4(PPh(3))(3) were unsuccessful, but NMR data show the formation of both heterobimetallic trans- and cis-ruthenium dihydride-uranium compounds X(2)U[mu(eta(5),eta(1))-TMP]Ru-2(H)(2)(PPh(3))(2) (X = BH4, Cl) in solution.