| 308086-78-4

• CAS: 308086-78-4
• 化学式: C₂₂H₂₉AlN₂O
• 分子量: 364.467
• InChiKey: KBJHLSGJOADNGD-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-[(2-aminophenylimino)methyl]-4,6-di-tert-butylphenol 、 三甲基铝 以 甲苯 为溶剂， 以78%的产率得到
  参考文献：
  名称：

  Group 13 Cation Formation with a Potentially Tridentate Ligand

  摘要：

  A potentially tridentate ligand, Phensal(tBu)H-3, was prepared by the condensation of 1 equiv of phenylenediamine with 3,5-di-tert-butylsalicylaldehyde, When 1 equiv of this new ligand is added to AlMe3 [[Phensal(tBu)HAlMe]](2) (1) results. In contrast, this reaction with GaMe3 produces [Phensal(tBu)H-2]GaMe2 (2). When 1 or 2 equiv of Phensal(tBu)Hs is combined with Et2AlCl, the,complex [Phensal(tBu)](2)AlCl (3) forms. However the same reaction with Me2GaCl leads to. [Phensal(tBu)Ha] Ga(Me)Cl (4). A cationic complex, {[Phensal(tBu)](2)Al}Cl-+(-) (5), is formed when 3 is dissolved in MeOH. The MeOH apparently mediates the formation of the cation but does not coordinate the cationic metal, when the solvent is removed, 5 reverts back to neutral 3. When 3 is combined with GaCl3 in toluene, another cationic complex, {[Phensal(tBu)H-2](2)Al}+GaCl4- (6), is formed. In a similar manner, {[Phensal(tBu)H-2](2)Al}+Me2AlCl2- (7) is formed by adding Me2AlCl to 3. The compounds were characterized by mp, elemental analyses, IR, H-1 smd Al-27 NMR, and in the case of 2, 5, and 6 single-crystal X-ray analysis.

  DOI：

  10.1021/om000058m