trans-[Fe(II)Br2(4-I-pyrazole)4][Fe(III)Br4]*CH2Cl2 | 1400114-99-9

• 英文名称: trans-[Fe(II)Br2(4-I-pyrazole)4][Fe(III)Br4]*CH2Cl2
• CAS: 1400114-99-9
• 化学式: Br₄Fe*CH₂Cl₂*C₁₂H₁₂Br₂FeI₄N₈
• 分子量: 1451.95
• InChiKey: KMPBEMYFINNQEN-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  4-碘吡唑 、 ferric(III) bromide 、 二氯甲烷 反应 20.0h， 以78%的产率得到trans-[Fe(II)Br2(4-I-pyrazole)4]*2H2O
  参考文献：
  名称：

  Structural and 57Fe-Mössbauer characterization of mononuclear ferrous and ferric pyrazole complexes

  摘要：

  The reactions of FeX3 (X = Cl and Br) and pz*H (pz*H = pyrazole, or substituted pyrazole) in CH2Cl2 have led to three types of mononuclear complexes: mer-[FeX3(pz*H)(3)], trans-[FeX2(pz*H)(4)](-) and trans-[FeX2(pz*H)(4)]. The latter type, containing Fe-II-centers results from spontaneous reduction of the Fe-III starting material. The X-ray crystal structures of eleven such complexes and the Fe-57-Mossbauer spectra of three of them are reported. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.07.052