| 936740-59-9

• CAS: 936740-59-9
• 化学式: C₃₀H₃₀Cu₃F₁₂N₄O₁₀
• 分子量: 1025.21
• InChiKey: RAPZCNJXZSHHDD-GQYZVRRXSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(II) trifluoroacetate 、 (2-[1-(2-dimethylaminoethylimino)methyl]phenol) 以 甲醇 为溶剂， 以75%的产率得到
  参考文献：
  名称：

  An antiferromagnetically coupled trinuclear Cu(II) complex containing μ(O,O′), μ(O) carboxylates and μ(O) phenoxide bridges

  摘要：

  The trinuclear complex [L2Cu3(CF3CO2)(4)] (1) has been synthesized and its crystal structure determined. It consists of a linear arrangement of Cu(II) centers. The central copper atom is bonded to six oxygen atoms and has a tetragonally distorted octahedral geometry, while the terminal copper atoms are bonded to three oxygen and two nitrogen atoms and show a distorted square pyramidal geometry. The complex shows di-mu(O,O') syn-syn carboxylate bridging as well as monoatomic (mu-O) bridging, along with phenolate (mu-O) oxygen bridging. Cryomagnetic investigations in the range 2-300 K revealed an antiferromagnetic spin exchange interaction with J = -95.7 cm(-1), based on the isotropic exchange model H-ex = -2J[S-1 center dot S-2 + S-2 center dot S-3]. (C) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.09.030