chloropalladium(1+);N-(2-ethenylphenyl)ethanimine;triethylphosphane | 403669-49-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: chloropalladium(1+);N-(2-ethenylphenyl)ethanimine;triethylphosphane
• CAS: 403669-49-8
• 化学式: C₂₂H₄₀ClNP₂Pd
• 分子量: 522.387
• InChiKey: QTHDJIUTXPXHSE-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  chloropalladium(1+);N-(2-ethenylphenyl)ethanimine;triethylphosphane 以 氯仿 为溶剂， 生成 dichlorobis(triethylphosphine)palladium(II)
  参考文献：
  名称：

  Structure and Reactivity of (η³-Indolylmethyl)palladium Complexes Generated by the Reaction of Organopalladium Complexes with o-Alkenylphenyl Isocyanide

  摘要：

  The reaction of methylpalladium complexes with o-alkenylphenyl isocyanides results in the successive intramolecular insertion of the alkenyl and isocyano groups followed by the 1,3-migration of hydrogen to give (eta(3)-indolylmethyl)palladium complexes (4) in good yields. Treatment of 4 with diethylamine causes nucleophilic attack at the exo methylene carbon to give 2-methyl-3-(aminomethyl)indole, whereas the reactions with HCl produce 2,3-dimethylindole derivatives.

  DOI：

  10.1021/om010897o
• 作为产物：
  描述：

  trans-chloro(methyl)bis(triethylphosphine)palladium(II) 、 2-isocyanostyrene 以 二氯甲烷 为溶剂， 以86%的产率得到chloropalladium(1+);N-(2-ethenylphenyl)ethanimine;triethylphosphane
  参考文献：
  名称：

  Structure and Reactivity of (η³-Indolylmethyl)palladium Complexes Generated by the Reaction of Organopalladium Complexes with o-Alkenylphenyl Isocyanide

  摘要：

  The reaction of methylpalladium complexes with o-alkenylphenyl isocyanides results in the successive intramolecular insertion of the alkenyl and isocyano groups followed by the 1,3-migration of hydrogen to give (eta(3)-indolylmethyl)palladium complexes (4) in good yields. Treatment of 4 with diethylamine causes nucleophilic attack at the exo methylene carbon to give 2-methyl-3-(aminomethyl)indole, whereas the reactions with HCl produce 2,3-dimethylindole derivatives.

  DOI：

  10.1021/om010897o