1-chloro-1-(trimethylsilyl)silacyclopentane | 521060-75-3

• 英文名称: 1-chloro-1-(trimethylsilyl)silacyclopentane
• 英文别名: (1-chlorosilolan-1-yl)-trimethylsilane
• CAS: 521060-75-3
• 化学式: C₇H₁₇ClSi₂
• 分子量: 192.836
• InChiKey: XTYLCVWJMLHBJT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.38
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  sodium dicarbonyl(cyclopentadienyl)ferrate 、 1-chloro-1-(trimethylsilyl)silacyclopentane 以 四氢呋喃 为溶剂， 以78%的产率得到(η5-C5H5)Fe(CO)2(1-(trimethylsilyl)silacyclopentyl)
  参考文献：
  名称：

  Photochemistry of the Three Possible Isomeric Cyclic Disilyliron Complexes, FpSi₂R₅ (Si₂R₅ = 1,2,2-Trimethyldisilacyclohexyl, (1-Methylsilacyclopentyl)dimethylsilyl, and 1-(Trimethylsilyl)silacyclopentyl, Fp = (η⁵-C₅H₅)Fe(CO)₂)

  摘要：

  The three cyclic disilyliron complexes FpSi2Re6 (Si2R5 = 1,2,2-trimethyldisilacyclohexyl (3), (1-methylsilacyclopentyl)dimethylsily (6), 1-(trimethylsilyl)silacyclopentyl (9) have been synthesized and characterized. Photolysis of these complexes resulted in the formation of FpSiMe3 and FpSiR3 (SiR3 = methylsilacyclopentyl) in the same ratio of 34:66 via silylene eliminations. Irradiation of 3,6, and 9 independently in the presence of HMPA led surprisingly to the formation of only the unique silylene intermediate [(eta(5)-C5H5)Fe(CO)-(=SiMe2.HMPA)(SiR3)], 11, which has been characterized by H-1, C-13, Si-29, C-13-H-1 COSY, C-13-H-1 COLOC, and Si-29-H-1 COLOC NMR spectroscopy.

  DOI：

  10.1021/om020823s