2-ferrocenyloxy-4-methyl-1,3,2-dioxaphosphane | 418806-71-0

• 英文名称: 2-ferrocenyloxy-4-methyl-1,3,2-dioxaphosphane
• CAS: 418806-71-0
• 化学式: C₁₄H₁₇FeO₃P
• 分子量: 320.108
• InChiKey: XLDWSVQKLDGFGK-WEWGPFMHSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  二(氰基苯)二氯化钯 、 2-ferrocenyloxy-4-methyl-1,3,2-dioxaphosphane 以 二氯甲烷 为溶剂， 以84%的产率得到
  参考文献：
  名称：

  Hydroxyferrocene as a prochiral analog of phenols: cyclopalladation of a mixed phosphite ester of hydroxyferrocene

  摘要：

  Hydroxyferrocene (ferrocenol), a metallocene analog of phenol, has been converted into a phosphite ester with chiral (racemic) butane-1,3-diol which undergoes cyclopalladation similarly to hydroxyarene phosphites. In this case, a planar chirality emerges but no diastereoselectivity has been observed. The molecular structure of the cyclopalladated product as pyridine add-act has been established by the X-ray study of a single crystal. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)01228-1
• 作为产物：
  描述：

  ferrocenol 、 2-Chloro-4-methyl-1,3,2-dioxaphosphorinane 在 Et₃N 作用下， 以 四氢呋喃 为溶剂， 以81.7%的产率得到2-ferrocenyloxy-4-methyl-1,3,2-dioxaphosphane
  参考文献：
  名称：

  Hydroxyferrocene as a prochiral analog of phenols: cyclopalladation of a mixed phosphite ester of hydroxyferrocene

  摘要：

  Hydroxyferrocene (ferrocenol), a metallocene analog of phenol, has been converted into a phosphite ester with chiral (racemic) butane-1,3-diol which undergoes cyclopalladation similarly to hydroxyarene phosphites. In this case, a planar chirality emerges but no diastereoselectivity has been observed. The molecular structure of the cyclopalladated product as pyridine add-act has been established by the X-ray study of a single crystal. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)01228-1