[RuCl(η6-p-cymene)(MeS-C6H4-2-N=CH-C6H5)][PF6] | 879690-54-7

• 英文名称: [RuCl(η6-p-cymene)(MeS-C6H4-2-N=CH-C6H5)][PF6]
• CAS: 879690-54-7
• 化学式: C₂₄H₂₇ClNRuS*F₆P
• 分子量: 643.038
• InChiKey: QKQSBZXOEXJXKA-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 、 benzylidene-(2-methylsulfanyl-phenyl)-amine 以 甲醇 为溶剂， 以67%的产率得到[RuCl(η6-p-cymene)(MeS-C6H4-2-N=CH-C6H5)][PF6]
  参考文献：
  名称：

  Synthesis, structure, and characterization of some ruthenium arene complexes of N-(arylmethylene)-2-(methylthio)anilines and 2-(methylthio)aniline

  摘要：

  A series of cationic, half-sandwich ruthenium complexes with the general formula [(eta(6)-p-cymene)RuCl(MeS-C6H4-2-N=CHAr)][PF6] (3a-h), have been prepared from the reaction of [(eta(6)-p-cymene)RuCl2](2) with various N,S-donor Schiff base ligands derived from 2-(methylthio)aniline and several substituted benzaldehydes. The related aniline complex [(eta(6)-p-cymene)RuCl(MeS-C6H4-2-NH2)][PF6] (4) was synthesized from 2-(methylthio)aniline. All of the ruthenium complexes were characterized by IR, H-1 NMR, and UV/Vis spectroscopies. The molecular structure of complex 4 was determined by X-ray crystallography. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.06.017