[Mn(quinoline-2-carbaldehyde benzoyl hydrazone)Cl2] | 1261372-59-1

• 英文名称: [Mn(quinoline-2-carbaldehyde benzoyl hydrazone)Cl2]
• 英文别名: [Mn(HQCB)Cl2]
• CAS: 1261372-59-1
• 化学式: C₁₇H₁₃Cl₂MnN₃O
• 分子量: 401.154
• InChiKey: UEHSNTMUGPZXBC-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  benzoic acid (quinolin-2-yl)methylenehydrazide 、 manganese (II) acetate tetrahydrate 以 甲醇 为溶剂， 以52%的产率得到[Mn(quinoline-2-carbaldehyde benzoyl hydrazone)Cl2]
  参考文献：
  名称：

  Mn(II) complexes of some acylhydrazones with NNO donor sites: Syntheses, a spectroscopic view on their coordination possibilities and crystal structures

  摘要：

  Mn(II) complexes derived from a set of acylhydrazones were synthesised and characterized by elemental analyzes, IR, UV-vis and X-band EPR spectral studies as well as conductivity and magnetic susceptibility measurements. In the reported complexes, the hydrazones exist either in the keto or enolate form, as evidenced by IR spectral data. Crystal structures of two complexes are well established using single crystal X-ray diffraction studies. In both of these complexes two equivalent monoanionic ligands are coordinated in a meridional fashion using cis pyridyl, trans azomethine nitrogen and cis enolate oxygen atoms positioned very nearly perpendicular to each other. EPR spectra in DMF solutions at 77 K show hyperfine sextets and in some of the complexes the low intensity forbidden lines lying between each of the two hyperfine lines are also observed. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.09.007