[FcC(OTMS)(CN)(p-MeOC6H4)] | 638222-79-4

• 英文名称: [FcC(OTMS)(CN)(p-MeOC6H4)]
• CAS: 638222-79-4
• 化学式: C₂₂H₂₅FeNO₂Si
• 分子量: 419.379
• InChiKey: LZTHSMWBBHLPLM-ZEECNFPPSA-N

反应信息

• 作为产物：
  描述：

  4-methoxybenzoylferrocene 、 三甲基氰硅烷 在 zinc(II) iodide 作用下， 以 二氯甲烷 为溶剂， 以71.5%的产率得到[FcC(OTMS)(CN)(p-MeOC6H4)]
  参考文献：
  名称：

  Synthesis of cyanohydrin trimethylsilyl ethers of acylferrocenes

  摘要：

  The addition of trimethylsilyl cyanide to acylferrocenes FcCOR (R. = Me, Et, Pr-n, Pr-i, Ph, p-MeOC6H4, o-ClC6H4, m-ClC6H4, p-ClC6H4, Fc; Fc = C5H4FeC5H5) catalyzed by zinc iodide in methylene chloride provided the corresponding cyanohydrin trimethylsilyl ethers in moderate to high yields. Factors affecting the reaction and yields of adducts were investigated. All new compounds were characterized by IR and H-1 NMR spectroscopies. In addition, the adducts of p-chlorobenzoylferrocene and diferrocenyl ketone were structurally determined by X-ray crystallography. (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(03)00262-6