(η-1-tBuNH-1,7,9-tricarbollide)(1,5-cyclooctadiene)rhodium | 859217-55-3

• 英文名称: (η-1-tBuNH-1,7,9-tricarbollide)(1,5-cyclooctadiene)rhodium
• 英文别名: [1-cod-12-tBuNH-1,2,4,12-RhC3B8H10]；(η-1-tBuNH-1,7,9-C3B8H10)Rh(cod)
• CAS: 859217-55-3
• 化学式: C₁₅H₃₂B₈NRh
• 分子量: 415.819
• InChiKey: LXYHEYYKJBNJFC-GCOBPYNFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  (η-1-tBuNH-1,7,9-tricarbollide)(1,5-cyclooctadiene)rhodium 、 碘 以 乙醚 为溶剂， 以96%的产率得到[(η-1-tBuNH-1,7,9-C3B8H10)RhI2]2
  参考文献：
  名称：

  The first (tricarbollide)rhodium halide complexes

  摘要：

  Reactions of (eta-1-(BuNH)-Bu-t-1,7,9-C3B8H10)Rh(cod) with Br-2 or I-2 give complexes [(eta-1-(BuNH)-Bu-t-1,7.9-C3B8H10) RhX2](2) (X=Br (2a), I (2b)). Reaction of 2b with TIBF4 affords cation [(eta-1-(BuNH)-Bu-t-1,7.9-C3B8H10)(2)Rh-2(mu-I)(3)](+) (3). Complex 2a reacts with Tl[Tl(eta-7,8-C2B9H11)] giving the bis(carborane) complex (eta-1-(BuNH)-Bu-t-1,7,9-C3B8H10)Rh (eta-7,8-C2B9H11) (4). Structures of 2a,b were determined by X-ray diffraction.] (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2010.11.024
• 作为产物：
  描述：

  四氢呋喃 、 Tl(+)[7-t-BuNH-nido-7,8,9-C3B8H10](-) 、 chloro(1,5-cyclooctadiene)rhodium(I) dimer 在 AgOTf 作用下， 以 四氢呋喃 为溶剂， 以96%的产率得到(η-1-tBuNH-1,7,9-tricarbollide)(1,5-cyclooctadiene)rhodium
  参考文献：
  名称：

  Metal complexes with an aminosubstituted tricarbollide ligand

  摘要：

  The reaction of the tricarbollide salt Tl[7-tBuNH-7,8,9-C3B8H10] (Tl1) with [(cod)Rh(THF)(x)](+) gives the rhodium complex [1(cod)-12-tBuNH-1,2,4,12-RhC3B8H10] in almost quantitative yield. Analogous reactions of Tl1 with [(ring)M(THF)(x)](2+) ((ring)M = Cp*Rh and (1,3,5-C6H3Me3)Ru) afford the corresponding metallatricarbollides [1-(ring)-12-tBuNH-1,2,4,12-MC3B8H10] in ca. 50% yield. Refluxing Tl1 with [Mn(CO)(3)(MeCN)(3)](+) in THF give the tricarbollide analogue of eymantrene, [1,1,1-(CO)(3)-12-tBuNH-1,2,4,12-MnC3B8H10], the structure of which was determined by single-crystal X-ray diffraction analysis. In all cases, the formation of the metallatricarbollide complexes is accompanied by polyhedral rearrangement leading to the maximum separation of the cage carbon atoms. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.01.039