[Pd(η3-C3H5)(2-[3,5-bis(4-butoxyphenyl)pyrazol-1-yl]pyridine)][CF3SO3] | 897935-42-1

• 英文名称: [Pd(η3-C3H5)(2-[3,5-bis(4-butoxyphenyl)pyrazol-1-yl]pyridine)][CF3SO3]
• CAS: 897935-42-1
• 化学式: CF₃O₃S*C₃₁H₃₆N₃O₂Pd
• 分子量: 738.136
• InChiKey: UTXPDVNDEKUJGY-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  bis(η3-allyl-μ-chloropalladium(II)) 、 silver trifluoromethanesulfonate 、 丙酮 、 2-[3,5-bis(4-butoxyphenyl)-pyrazol-1-yl]pyridine 以 二氯甲烷 、 丙酮 为溶剂， 以60%的产率得到[Pd(η3-C3H5)(2-[3,5-bis(4-butoxyphenyl)pyrazol-1-yl]pyridine)][CF3SO3]
  参考文献：
  名称：

  Molecular architectures of cationic [Pd(η3-C3H5)(pzbp2py)]+ complexes and and as counteranions (pzbp2py=2-[3,5-bis(4-butoxyphenyl)pyrazol-1-yl]pyridine)

  摘要：

  The crystal structures of two complexes containing the 2-[3,5-bis(4-butoxyphenyl)pyrazol-1-yl]pyridine (pz(bp2)py) ligand bonded to the [Pd(eta(3)-C3H5)](+) fragment and BF4- and CF3SO3- as counteranions (1 and 2, respectively) have been solved and their molecular architectures compared. The compounds exhibit a D-2 network based on weak interactions in which the counterion plays an important role. The molecular layers in the D-2 arrangement show interpenetration between the substituent-chains on the pyrazole rings. These features are also observed in related compounds bearing only one chain on the pyrazole ring. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.12.071