(2-[(4-benzyl-1H-1,2,3-triazol-1-yl)methyl]pyridine)PdCl2 | 1253045-32-7

• 英文名称: (2-[(4-benzyl-1H-1,2,3-triazol-1-yl)methyl]pyridine)PdCl2
• CAS: 1253045-32-7
• 化学式: C₁₄H₁₂Cl₂N₄Pd
• 分子量: 413.602
• InChiKey: HWZSCWVFMOBZJL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (2-[(4-benzyl-1H-1,2,3-triazol-1-yl)methyl]pyridine)PdCl2 、 二甲基亚砜 以 二甲基亚砜 为溶剂， 生成 (dimethyl sulfoxide)2PdCl2
  参考文献：
  名称：

  Palladium(II) and platinum(II) complexes of bidentate 2-pyridyl-1,2,3-triazole “click” ligands: Synthesis, properties and X-ray structures

  摘要：

  The synthesis and characterization of palladium(II) and platinum(II) complexes of isomeric bidentate 2-pyridyl-1,2,3-triazole "click" ligands is reported. The complexes have been fully characterized by elemental analysis, HRESI-MS, IR, UV-Vis, H-1 and C-13 NMR spectroscopy. Additionally, the molecular structures of the Pd(II) and Pt(II) complexes of the 2-[(4-phenyl-1H-1,2,3-triazol-1-yl)methyl]pyridine ligand are confirmed by X-ray crystallography. Solution studies indicate the 2-(1-benzyl-1H-1,2,3-triazol-4-yl)pyridine ligand forms more stable complexes with Pd(II) and Pt(II) than the isomeric 2[(4-phenyl-1H-1,2,3-triazol-1-yl)methyl]pyridine ligand. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.08.021
• 作为产物：
  描述：

  双(乙腈)氯化钯(II) 、 2-{[4-phenyl-1H-1,2,3-triazol-1-yl]methyl}pyridine 以 乙腈 为溶剂， 以76%的产率得到(2-[(4-benzyl-1H-1,2,3-triazol-1-yl)methyl]pyridine)PdCl2
  参考文献：
  名称：

  Palladium(II) and platinum(II) complexes of bidentate 2-pyridyl-1,2,3-triazole “click” ligands: Synthesis, properties and X-ray structures

  摘要：

  The synthesis and characterization of palladium(II) and platinum(II) complexes of isomeric bidentate 2-pyridyl-1,2,3-triazole "click" ligands is reported. The complexes have been fully characterized by elemental analysis, HRESI-MS, IR, UV-Vis, H-1 and C-13 NMR spectroscopy. Additionally, the molecular structures of the Pd(II) and Pt(II) complexes of the 2-[(4-phenyl-1H-1,2,3-triazol-1-yl)methyl]pyridine ligand are confirmed by X-ray crystallography. Solution studies indicate the 2-(1-benzyl-1H-1,2,3-triazol-4-yl)pyridine ligand forms more stable complexes with Pd(II) and Pt(II) than the isomeric 2[(4-phenyl-1H-1,2,3-triazol-1-yl)methyl]pyridine ligand. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.08.021