[Pd(N3,N7-ethylenediamine-N9-ethyladenine)Cl][PF6] | 909022-71-5

• 英文名称: [Pd(N3,N7-ethylenediamine-N9-ethyladenine)Cl][PF6]
• CAS: 909022-71-5
• 化学式: C₉H₁₅ClN₇Pd*F₆P
• 分子量: 508.102
• InChiKey: QFVXPBUKCROISL-UHFFFAOYSA-M

反应信息

• 作为反应物：
  描述：

  uracil disodium salt 、 [Pd(N3,N7-ethylenediamine-N9-ethyladenine)Cl][PF6] 以 水 、 N,N-二甲基甲酰胺 为溶剂， 生成 [Pd2(N3,N7-ethylenediamine-N9-ethyladenine)2(N1,N3-uracilate)][ClO4]2
  参考文献：
  名称：

  Conserved supramolecular architecture in polymetallic nucleobase complexes

  摘要：

  The single crystal X-ray structures of two different polynuclear metal-nucleobase complexes are reported. Crystals isolated from the reaction of CdBr2 with ethylenediamine-N9-ethyladenine, A-Et-en, were characterised by X-ray structural analysis as a coordination polymer [mu-{CdBr(N3,N7-A-Et-en)}(2)CdBr4] (2). Reaction of the Pd(II)-adenine complex, [PdCl(N3-A-Et-en)](+), with sodium uracilate yielded [(Pd(N3-A-Et-en)(2)(N1,N3-U)][ClO4](2) (3). Despite the considerable differences in the nature of the compounds the crystal structures feature essentially similar supramolecular architectures. A building block analysis demonstrates how this arises and reveals an approach, based on bond-type substitution and molecular replacement, to conserving such features. This may be a useful approach that could be more widely adopted in crystal engineering strategies. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.01.009