[6,6'-dimethoxybiphenyl-2,2'-diylbis(diphenylphosphane)-κ2P,P']hydrido[1-(η6-phenyl)ethanol]ruthenium(II) trifluoromethanesulfonate | 528572-60-3

• 英文名称: [6,6'-dimethoxybiphenyl-2,2'-diylbis(diphenylphosphane)-κ2P,P']hydrido[1-(η6-phenyl)ethanol]ruthenium(II) trifluoromethanesulfonate
• CAS: 528572-60-3
• 化学式: CF₃O₃S*C₄₆H₄₃O₃P₂Ru
• 分子量: 955.934
• InChiKey: KQGUNRSXCRCEIJ-DQKOFLAZSA-M

反应信息

• 作为产物：
  描述：

  三氟甲磺酸 、 苏合香醇 、 Ru(OAc)2((R)-MeOBIPHEP) 以 异丙醇 为溶剂， 以91%的产率得到[6,6'-dimethoxybiphenyl-2,2'-diylbis(diphenylphosphane)-κ2P,P']hydrido[1-(η6-phenyl)ethanol]ruthenium(II) trifluoromethanesulfonate
  参考文献：
  名称：

  A Facile Synthesis of a Wide Variety of Cationic Ruthenium Hydrido-Arene Complexes of binap (=1,1′-Binaphthalene-2,2′-diylbis(diphenylphosphane)) and MeObiphep (=6,6′-Dimethoxybiphenyl-2,2′-diylbis(diphenylphosphane))

  摘要：

  A straightforward high-yield synthetic route to the cationic hydrido-arene complexes [RuH(eta(6)-arene)(binap or MeO-biphep)](CF3SO3), with a variety of arenes containing both donor and acceptor substituents, is described. C-13-NMR Data for these complexes are reported. Several of these Ru-complexes have been used as transfer-hydrogenation catalysts in the reduction of acetophenone.

  DOI：

  10.1002/1522-2675(200211)85:11<3937::aid-hlca3937>3.0.co;2-x