Cu(2-(2,4,6-iPrC6H2)C6H4)(CNtBu) | 1319747-65-3

• 英文名称: Cu(2-(2,4,6-iPrC6H2)C6H4)(CNtBu)
• CAS: 1319747-65-3
• 化学式: C₄₇H₆₃CuN₄
• 分子量: 747.59
• InChiKey: SUBOPTBSOOCFFZ-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  异氰酸叔丁酯 、 Cu(2-(2,4,6-iPrC6H2)C6H4) 以 正庚烷 为溶剂， 以72%的产率得到Cu(2-(2,4,6-iPrC6H2)C6H4)(CNtBu)
  参考文献：
  名称：

  Sterically crowded triazenides as novel ancillary ligands in copper chemistry

  摘要：

  We have synthesized copper salts MN3RR ' derived from the biphenyl-or m-terphenyl-substituted triazenes Tph(2)N(3)H (1a) and Dmp(Tph)N3H (1b) (Dmp = 2,6-Mes(2)C(6)H(3) with Mes = 2,4,6-Me3C6H2; Tph = 2TripC(6)H(4) with Trip = 2,4,6-i-Pr3C6H2). The homoleptic copper triazenide [CuN(3)Tph(2)] (2a) was obtained in high yield from the metallation of 1a with mesityl copper in n-heptane, while the complex [CuN3(Dmp)Tph] (2b) was generated by the same method in situ only. Reaction of 2a with triphenylphosphane gave the 2:1 adduct [CuN(3)Tph(2)(PPh3)(2)] (3a), regardless of the used complex/ donor ratio, while reaction of 2a or 2b with a stochiometric amount of t-butylisonitrile afforded the 1:1 adducts [Tph(2)N(3)CuCNtBu] (4a) and [Dmp(Tph) N(3)CuCNtBu] (4b). All new compounds (except 2b) have been characterized by H-1 NMR, C-13 NMR and IR spectroscopy, elemental analysis, melting point (not 2a), and X-ray crystallography. The IR spectroscopic examination of the v(C N) stretch in the isonitrile adducts 4a and 4b revealed the weaker donor character of the supporting triazenido ligands compared to related beta-diketiminato ligands. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.01.079