| 607719-22-2

• CAS: 607719-22-2
• 化学式: C₅₄H₆₆ClN₃P₃Ru*Cl
• 分子量: 1022.04
• InChiKey: BXYWTWYRIPTNEO-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  tris(triphenylphosphine)ruthenium(II) chloride 、 N-diphenylphosphanylcyclohexanamine 以 二氯甲烷 为溶剂， 以76%的产率得到
  参考文献：
  名称：

  Transition metal (Group 6, Ru and Group 10) derivatives of aminophosphines, Ph2PN(H)R (R=Ph, C6H11)

  摘要：

  The reactions of aminophosphines with Group 6 metal carbonyls afford both mono-substituted and disubstituted complexes. The reaction of Ph2PN(H)(6)H-11 with molybdenum tetracarbonyl derivative gives a mixture of cis and trans-isomers. The reaction of Ph2PN(H)Ph with Pd(COD)Cl-2 leads to the P-N bond cleavage to give chloro bridged dimer, [Pd(PPh2O)(PPh2OH)(mu-Cl)](2), whereas with Pt(COD)Cl-2, disubstituted cis-[PtCl2{PPh2N(H)R}(2)](2) was obtained. The reaction of Ph2PN(H)C6H11 with RuCl2(DMSO)(4) or RUCl2(PPh3)(3) leads to the formation of ionic complex, [RuCl{Ph2PN(H)C6H11}(3)]Cl. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(03)00543-6