dicarbonyl[1'-carboxy(2'-methoxyphenyl)][(1,2,3,4,5-η)-2,5-dimethoxy-2,4-cyclohexadienyl]iron(II) | 258841-83-7

• 英文名称: dicarbonyl[1'-carboxy(2'-methoxyphenyl)][(1,2,3,4,5-η)-2,5-dimethoxy-2,4-cyclohexadienyl]iron(II)
• CAS: 258841-83-7
• 化学式: C₁₈H₁₈FeO₆
• 分子量: 386.184
• InChiKey: UUCPXJMLDGHVFZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  tricarbonyl(η(5)-1,4-dimethoxycyclohexadienyl)iron hexafluorophosphate 、 2-溴苯甲醚 在 正丁基锂 作用下， 以 乙二醇二甲醚 、 正己烷 为溶剂， 以1%的产率得到dicarbonyl[1'-carboxy(2'-methoxyphenyl)][(1,2,3,4,5-η)-2,5-dimethoxy-2,4-cyclohexadienyl]iron(II)
  参考文献：
  名称：

  Addition of aryl substituents to cyclohexadienyliron electrophiles in the development of routes to C12 central building blocks for alkaloid synthesis

  摘要：

  Novel iron-aroyl complexes or synthetically prized arylcyclohexadienyl complexes can be formed from tricarbonyl(eta(5)-1,4-dimethoxycyclohexadienyl)iron(1 +) hexafluorophosphate(1 -) by correct control of reaction sequences that exploit the addition of aryllithium reagents to introduce the aromatic group. Bimetallic products are obtained when a tricarbonylchromium-bound aryllithium reagent or the corresponding cuprate are employed. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00390-4