dichloro(N,N,N',N'-tetramethylpropane-1,3-diamine)cobalt(II) | 15380-97-9

• 英文名称: dichloro(N,N,N',N'-tetramethylpropane-1,3-diamine)cobalt(II)
• 英文别名: dichlorocobalt;N,N,N',N'-tetramethylpropane-1,3-diamine
• CAS: 15380-97-9
• 化学式: C₇H₁₈Cl₂CoN₂
• 分子量: 260.133
• InChiKey: KLELIHZOQYVPNZ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  四甲基丙二胺 、 cobalt(II) chloride 以 二氯甲烷 为溶剂， 以70.1%的产率得到dichloro(N,N,N',N'-tetramethylpropane-1,3-diamine)cobalt(II)
  参考文献：
  名称：

  Complexes of metal(II) halides of the first transition series with N,N,N′,N′-tetramethylmethane-diamine, -ethane-1,2-diamine and -propane-1,3-diamine

  摘要：

  Complexes of metal(IT) halides of the first transition series with three diamines Me2N(CH2)(n)NMe2 have been studied. For n = 1 (tmmn), only dinuclear species [{MX2(tmmn)}(2)] have been isolated, whereas for n = 3 (tmpn) only tetrahedral mononuclear species [MX2(tmpn)] have been characterised. For n = 2 (tmen), structures of both kinds have been prepared. and also of a third kind, octahedral trans-[MX2(tmen)(2)]. These different structures are often interconvertible. The structural types are rationalised in terms of the dimensions of the diamines rather than of the properties of the metal(II) ions. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(00)00384-4