[Ga(η5-P3C2Bu(t)2)] | 440084-57-1

• 英文名称: [Ga(η5-P3C2Bu(t)2)]
• CAS: 440084-57-1
• 化学式: C₁₀H₁₈GaP₃
• 分子量: 300.897
• InChiKey: HXZVTUVCITWCEO-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  gallium(I) bromide 、 potassium 3,5-di-tert-butyl-1,2,4-triphosphacyclopentadienyl 以 四氢呋喃 、 甲苯 为溶剂， 以99%的产率得到[Ga(η5-P3C2Bu(t)2)]
  参考文献：
  名称：

  Synthesis and structural characterisation of the 3,5-di-tert-butyl-1,2,4-triphospholyl complexes of monovalent gallium and thallium, [M(η5-P3C2Bu2t)], M=Ga, Tl

  摘要：

  Treatment of a metastable toluene-THF solution of GaBr with Kp(3)C(2)BU(2)(t) led to the monomeric triphospholyl gallium(l) complex [Ga(eta(5)-P3C2Bu2t] (3). The corresponding thallium complex [Tl(eta(5)-P3C2Bu2t)] (4) was prepared in a similar manner by treatment of TlCl with [Li(tmeda)(2)][(P3C2Bu2t)], Both complexes, which are monomeric in solution and in the gas phase, were characterised by mass spectrometry and multinuclear NMR spectroscopy. X-ray structure analyses of both complexes showed them to consist of weakly interacting monomeric half sandwich units in the solid state. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)01253-0