trans-[PtCl4(NH=C(Et)ON=C(H)Me)2] | 657385-11-0

• 英文名称: trans-[PtCl4(NH=C(Et)ON=C(H)Me)2]
• CAS: 657385-11-0
• 化学式: C₁₀H₂₀Cl₄N₄O₂Pt
• 分子量: 565.186
• InChiKey: KSNPVSFWLVRDKT-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  trans-[PtCl4(NH=C(Et)ON=C(H)Me)2] 以 氘代氯仿 为溶剂， 生成 trans-[PtCl4(NH=C(Et)OH)2]
  参考文献：
  名称：

  The first example of ligand-mediated dehydration of aldoximes

  摘要：

  The nitrile complex trans-[PtCl4(EtCN)(2)] reacts with the aldoximes HON=C(H)R [R = C(Ph)(=O), Me, Ph] in CH2Cl2 to afford kproducts of the addition of the aldoxime HON group across the nitrile CN triple bond, i.e. trans-[PtCl4{NH=C(Et)ON=C(H)R}(2)] (1-3). These compounds were characterized by elemental analyses, FAB MS. IR and H-1 and C-13{H-1} spectroscopies and X-ray structure determination has been performed for 1. In CHCl3 solution, 1-3 undergo the spontaneous imine ligand splitting to achieve the carboxamide complex trans-[PtCl4{NH=C(Et)OH}(2)] and RCN thus giving the first example of a ligand-mediated dehydration of aldoximes. The carboxamide and RCN products are also formed upon treatment of trans-[PtCl4(EtCN)(2)] with 2 equiv. of HON=C(H)R in CH2Cl2. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(03)00275-5
• 作为产物：
  描述：

  乙醛肟 、 trans-[PtCl4(propiononitrile)2] 以 二氯甲烷 为溶剂， 以78%的产率得到trans-[PtCl4(NH=C(Et)ON=C(H)Me)2]
  参考文献：
  名称：

  The first example of ligand-mediated dehydration of aldoximes

  摘要：

  The nitrile complex trans-[PtCl4(EtCN)(2)] reacts with the aldoximes HON=C(H)R [R = C(Ph)(=O), Me, Ph] in CH2Cl2 to afford kproducts of the addition of the aldoxime HON group across the nitrile CN triple bond, i.e. trans-[PtCl4{NH=C(Et)ON=C(H)R}(2)] (1-3). These compounds were characterized by elemental analyses, FAB MS. IR and H-1 and C-13{H-1} spectroscopies and X-ray structure determination has been performed for 1. In CHCl3 solution, 1-3 undergo the spontaneous imine ligand splitting to achieve the carboxamide complex trans-[PtCl4{NH=C(Et)OH}(2)] and RCN thus giving the first example of a ligand-mediated dehydration of aldoximes. The carboxamide and RCN products are also formed upon treatment of trans-[PtCl4(EtCN)(2)] with 2 equiv. of HON=C(H)R in CH2Cl2. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(03)00275-5