di[chloro-[2-(p-chlorophenylazo)pyrimidine](μ-chloro)-mercury(II)] | 582322-73-4

• 英文名称: di[chloro-[2-(p-chlorophenylazo)pyrimidine](μ-chloro)-mercury(II)]
• CAS: 582322-73-4
• 化学式: C₂₀H₁₄Cl₆Hg₂N₈
• 分子量: 980.283
• InChiKey: YKWJQVRHLVNTGG-GCSNRLHLSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-(p-chlorophenylazo)pyrimidine 、 mercury dichloride 以 甲醇 为溶剂， 生成 di[chloro-[2-(p-chlorophenylazo)pyrimidine](μ-chloro)-mercury(II)]
  参考文献：
  名称：

  Synthesis, spectral characterization and X-ray crystal structures of mercury(II)-azoimine compounds

  摘要：

  1-Ethyl-2-(phenylazo)imidazole (PaiEt, 2) and 2-(arylazo)pyrimidines (Raapm) (R=H (3a), p-Me (3b), p-Cl (3c)) are used to synthesize mercury(II) compounds. The complexes are characterized by elemental analysis, IR, UV-Vis, H-1 NMR spectral data and single crystal X-ray structures of di[chloro-{1-ethyl-2-(phenylazo)imidazole}(mu-chloro)-mercury(II)] (4) and di[chloro-{2-(phenylazo)pyrimidine) (mu-chloro)-mercury(II)] (5a). The first complex is a centro-symmetric dimer with two highly asymmetric chlorobridges which make the rhombohedral plane. The second complex forms an unsymmetric trapezohedral geometrical structure. (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(03)00109-8