tetratolylporphyrin-hydroxy-gallium(III) | 65930-59-8

• 英文名称: tetratolylporphyrin-hydroxy-gallium(III)
• CAS: 65930-59-8
• 化学式: C₄₈H₃₇GaN₄O
• 分子量: 755.571
• InChiKey: PLSQQVPYGJJFMX-HTMHXADGSA-M

反应信息

• 作为产物：
  描述：

  Ga(acac)₃ 、 5,10,15,20-tetrakis(4-methylphenyl)porphyrin 在 苯酚 作用下， 以 further solvent(s) 为溶剂， 生成 tetratolylporphyrin-hydroxy-gallium(III)
  参考文献：
  名称：

  Photophysical properties of gallium hydroxyl tetratolylporphyrin and 132-demethoxycarbonyl-(gallium hydroxyl)–methyl-pheophorbide a

  摘要：

  Two metal tetrapyrroles containing gallium, gallium hydroxyl tetratolylporphyrin and 13(2)-demethoxycarbonyl-(gallium hydroxyl)methyl pheophorbide a (Ga-(OH)-chlorin), were synthesized from their respective free bases using Ga(III)-acetylacetonate in a phenol melt. Their photophysical properties were investigated and the quantum yields of different monomolecular deactivation processes were determined. For Ga-(OH)-porphyrin S-2-fluorescence was observed and quantified. In contrast. for Ga-(OH)-chlorin no S-2-fluorescence was observed. Both compounds should be useful as efficient photosensitizers in photodynamic therapy. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.cplett.2005.10.131