{[Pb(η²-OOC(η⁵-C₅H₄)Fe(η⁵-C₅H₄)COC₂H₄COO-η²)(phen)]₂(CH₃OH)} | 1449607-77-5

• 英文名称: {[Pb(η²-OOC(η⁵-C₅H₄)Fe(η⁵-C₅H₄)COC₂H₄COO-η²)(phen)]₂(CH₃OH)}
• 英文别名: {[Pb(η²-(1'-(formyl)ferrocene-1-succinate)-η²)(1,10-phenanthroline)]₂(CH₃OH)}
• CAS: 1449607-77-5
• 化学式: CH₄O*C₅₄H₄₀Fe₂N₄O₁₀Pb₂
• 分子量: 1463.07
• InChiKey: UDPCIMMYECQOLS-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  甲醇 、 1,10-菲罗啉 、 、 lead(II) acetate trihydrate 反应 168.0h， 以65%的产率得到{[Pb(η²-OOC(η⁵-C₅H₄)Fe(η⁵-C₅H₄)COC₂H₄COO-η²)(phen)]₂(CH₃OH)}
  参考文献：
  名称：

  Syntheses, Structures, and Characterization of Two New Complexes Constructed From Asymmetric Ferrocenyldicarboxylate Ligand

  摘要：

  Asymmetric ligand 1-(formyl)ferrocene-1-succinic acid and two new complexes, {[Pb( 2-OOCFcCOC2H4COO- 2)(phen)]2 (CH3OH)} (1), {[Zn( 2 -OOCFcCOC2H4COO- 2)(phen)]2 (CH3OH)(H2O)} (2) [Fc = ( 5-C5H4)Fe( 5-C5H4), phen = 1,10-phenanthroline] have been synthesized and characterized. Single-crystal X-ray crystallographic analyses reveal that both complexes 1 and 2 present dimeric structures coordinated by carboxyl groups and phen units. Interestingly, various center dot center dot center dot interactions or Pb center dot center dot center dot interactions are discovered, which extend the two dimers to infinite 3-D supramolecular networks. Furthermore, the thermal analyses results are in reasonable agreement with the crystal structure analyses of complexes 1 and 2.

  DOI：

  10.1080/15533174.2012.754765