[(FeSalophen)₂O] | 18601-73-5

• 英文名称: [(FeSalophen)₂O]
• CAS: 18601-73-5
• 化学式: C₄₀H₂₈Fe₂N₄O₅
• 分子量: 756.38
• InChiKey: DTRWJUSHXNYHEM-SKCUSQGPSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [(FeSalophen)₂O] 、 5-[3,6,7,10,11-Pentakis(4-carboxybutoxy)triphenylen-2-yl]oxypentanoic acid 以 乙醇 为溶剂， 以64%的产率得到[C18H6(O(CH2)4COO(iron(bis(salicylidene)-o-phenylenediamine)))6]
  参考文献：
  名称：

  The (salophen)-bridged Fe/Cr (III) capped complexes with triphenylene core: Synthesis and characterization

  摘要：

  This article describes synthesis of the difference carboxylic acid derivatives of triphenylene and its complexation properties with Fe/Cr (III)-salophen. For this purpose, the carboxylic acid derivatives of 2,3,6,7,10,11-hexahydroxytriphenylene were synthesized and then reacted with four new Fe(III) and Cr(III) complexes involving tetradenta Schiff bases bis(salicylidene)-o-phenylenediamine-(salophenH(2)). The prepared compounds were characterized by means of elemental analysis carrying out infrared spectroscopy (IR), thermogravimetric analysis (TG), nuclear magnetic resonance (H-1 NMR), elemental analysis and magnetic susceptibility measurement. The complexes can also be characterized as low-spin distorted octahedral Fe(III) and Cr (III) bridged by carboxylic acids. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2011.06.020
• 作为产物：
  描述：

  以 甲醇 、 水 为溶剂， 生成 [(FeSalophen)₂O]
  参考文献：
  名称：

  Syntheses, characterization and X-ray crystal structures of hexa-coordinated monomeric and oxo-bridged dimeric Fe(III) compounds with salen-type Schiff bases

  摘要：

  Five Fe(III) compounds, [Fe(salophen)(N-3)(MeOH)] (1) [Fe(salophen)(NCS)(MeOH)] (2), [Fe(vanophen)(Hlm)(2)]ClO4 (3), [(mu-O){Fe(vanophen))(2)]center dot 2H(2)O (4) and [(mu-O){Fe(naphophen)}(2)]center dot 2CH(2)Cl(2) (5) where, H(2)salophen = N,N'-bis(salicylidene)phenylediamine, H(2)vanophen = N,N'-(1,2-phenylene)-bis(3-methoxy-salicylideneimine) and H(2)naphophen = NN'-bis(2-hydroxy-1-naphthaldehyde)-1,2-phenylenediimine, have been prepared and characterized by elemental analysis, IR and UV-Vis spectroscopy and single-crystal X-ray diffraction studies. In compounds 1, 2 and 3, Fe(III) has six-coordinated pseudo-octahedral geometry in which the O(1), O(2), N(1) and N(2) atoms of the deprotonated di-Schiff base constitute the equatorial plane. Both in compounds 1 and 2, methanol molecules are present in the fifth coordination sites in apical positions. The sixth coordination sites are occupied by one N atom of an azide in compound 1 and an N atom of thiocyanate in compound 2. In compound 3, both axial positions are occupied by nitrogen atoms from two different imidazole molecules. In both compounds 4 and 5, Fe(III) has a five-coordinated square pyramidal geometry with bridging oxygen atoms in the axial positions. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.08.085

文献信息

• The synthesis and characterization of [M(salen/salophen/saldeta)] [M=Cr(III), Mn(III) or Fe(III)] capped s-triazine cored tripodal trinuclear Schiff bases complexes
  作者：Berkman İşçi、Şaban Uysal

  DOI：10.1007/s10847-018-0844-7

  日期：2018.12

  bases complexes were synthesized with the reaction of 8 and/or 9 and ligand complexes. The complexes have been characterized as low-spin (S = 1/2) distorted octahedral Fe(III)Salen/Salophen, low-spin (S = 1) distorted octahedral Mn(III)Salen/Salophen, high-spin (S = 5/2) distorted octahedral Fe(III)Saldeta, high-spin (S = 2) distorted octahedral Mn(III)Saldeta and (S = 3/2) distorted octahedral Cr(II

  配体复合物 ([M(salen/salophen)]2O、[M(saldeta)]Cl 缩写为 LC、M=Cr(III)、Mn(III) 或 Fe(III))，已被合成。2,4,6-三(4-甲酰基苯氧基)-1,3,5-三嗪 (3) 通过对羟基苯甲醛 (2) 和氰尿酰氯 (1) 的反应合成。2,4,6-三(4-(4'-羧基苯基亚氨基)苯氧基)-1,3,5-三嗪(5)与2,4,6-三(4-甲酰基苯氧基)-1反应合成， 3,5-三嗪 (3) 和 4-氨基苯甲酸 (4)。2,4,6-三(4-(4-羧基苯基亚氨基)苯氧基)-1,3,5-三嗪在 CH3CN 中用 SOCl2 和 2,4,6-三(4-(4'-氯甲酰基苯基亚氨基)苯氧基处理)-1,3,5-三嗪(6)被获得。2,4,6-三(4-(4'-氯甲酰基苯基亚氨基)苯氧基)-1,3,5-三嗪在CH3CN中与4-氨基苯甲酸或4-羟基苯甲酸反应，2,4,6-三(
• Reactions of Chloroiron(III) Schiff Base Complexes with Superoxide Ion in Dimethyl Sulfoxide
  作者：Takayuki Matsushita、Hiroshi Kono、Mitsuru Nishino、Toshiyuki Shono

  DOI：10.1246/bcsj.55.2581

  日期：1982.8

  A series of monomeric chloroiron(III) complexes with the quadridentate or quinquedentate Schiff bases such as N,N′-disalicylideneethylenediamine or bis[3-(salicylideneamino)propyl]amine react with superoxide ions, O2−, in dimethyl sulfoxide to give the corresponding μ-oxo dimers. The polymeric chloroiron(III) complexes with the polymeric (oligomeric) Schiff bases derived from 5,5′-methylenedisalicylaldehyde

  一系列单体氯亚铁 (III) 与四齿或五齿希夫碱（如 N,N'-二水杨基乙二胺或双[3-（水杨基氨基）丙基]胺）在二甲亚砜中与超氧离子 O2- 反应，得到相应的μ-氧代二聚体。聚合氯铁 (III) 与衍生自 5,5'-亚甲基水杨醛和三胺的聚合（低聚）席夫碱络合物与二甲亚砜中的 O2- 反应生成含氧络合物，可能是双氧加合物 FeIII-O2-。吸收光谱和极谱测量表明了这一点。
• A Straightforward Electrochemical Approach to Imine- and Amine-bisphenolate Metal Complexes with Facile Control Over Metal Oxidation State
  作者：Michael R. Chapman、Susan E. Henkelis、Nikil Kapur、Bao N. Nguyen、Charlotte E. Willans

  DOI：10.1002/open.201600019

  日期：2016.8

  are diverse, with the route chosen being dependent upon many factors such as metal–ligand combination and metal oxidation state. In this work we have shown that electrochemical methodology can be employed to synthesize a variety of metal–salen/salan complexes which comprise diverse metal–ligand combinations and oxidation states. Broad application has been demonstrated through the preparation of 34 complexes

  制备有机金属和配位化合物（例如希夫碱配合物）的合成方法多种多样，所选择的路线取决于许多因素，例如金属-配体组合和金属氧化态。在这项工作中，我们表明电化学方法可用于合成各种金属-salen/salan配合物，其中包含不同的金属-配体组合和氧化态。通过在温和环境条件下制备 34 种复合物，已证明了其广泛的应用。通过简单修改反应条件，可以实现对金属氧化态（M II/III/IV ，其中 M=Fe、Mn）前所未有的控制。沿着这条路线，描述了一个通用的协议转换，它允许获得分析纯的 Fe II/III –salen 配合物。还提出了调节电化学势、Mn/Ni 合金的选择性金属化，专门以高产率提供 Mn II/IV –salen 配合物。
• The Synthesis and Characterization of s-Triazine-Cored Tripodal Structure and Its Salen/Salophen-Bridged Fe/Cr(III) Capped Complexes
  作者：Erhan Karatas、Halil Ismet Ucan

  DOI：10.1002/jhet.2642

  日期：2017.1

  and Cr(III) complexes including tetradentate Schiff bases N,N′‐bis(salicylidene)ethylenediamine (salenH2)/bis(salicylidene)‐o‐phenylenediamine (SalophenH2). The synthesized ligand and complexes were characterized by means of elemental analysis carrying out 1H NMR, FTIR spectroscopy, thermal analyses, and magnetic susceptibility measurements. Finally, metal ratios of the prepared complexes were determined

  合成了一种新型的席夫碱化合物，并研究了其与Fe（III）和Cr（III）的络合性能。三脚架配体是通过s-三嗪和4-羟基苯甲醛反应合成的。然后通过5-氨基甲基-8-羟基喹啉（QN）与2,4,6-三（对甲酰苯氧基）-1,3,5-三嗪（TRIPOD）的反应合成涉及8-羟基喹啉的席夫碱/ chloroform介质。然后将获得的席夫碱（QN-TRIPOD）与四种三核Fe（III）和Cr（III）络合物反应，包括四齿席夫碱N，N'-双（水杨基）乙二胺（salenH 2）/双（水杨基）-o苯二胺（SalophenH 2）。通过进行1 H NMR的元素分析，FTIR光谱，热分析和磁化率测量来表征合成的配体和配合物。最后，通过原子吸收光谱法确定所制备的配合物的金属比。
• The synthesis and characterization of (MSalen/salophen/saldeta/salpy) [M=Fe(III) or Cr(III)] capped heteromultinuclear schiff bases-dioxime Ni(II) complexes: Their thermal and magnetic behaviours
  作者：Şaban Uysal、Ziya Erdem Koç

  DOI：10.1016/j.molstruc.2018.03.101

  日期：2018.8

  Abstract Chlorophenylglyoxime and Ligand Complexes ([M(Salen/Salophen)]2O, [M(Saldeta/Salpy)Cl] shortened as LC, M = Fe(III) or Cr(III)) have been synthesized. 3,5-dicarboxyanilinophenylglyoxime (5) and 4-carboxyphenylhydrazinophenylglyoxime (6) have been synthesized with the reaction of chlorophenylglyoxime and 5-aminoisophtalalic acid or 4-hydrazinobenzoic acid. [M(Salen/Salophen/Saldeta/Salpy)-3

  摘要 氯苯乙醛肟和配体配合物（[M(Salen/Salophen)]2O，[M(Saldeta/Salpy)Cl] 缩写为 LC，M = Fe(III) 或 Cr(III)）已被合成。3,5-二羧基苯胺基苯基乙醛肟 (5) 和 4-羧基苯基肼基苯基乙醛肟 (6) 已通过氯苯基乙醛肟与 5-氨基间苯二甲酸或 4-肼基苯甲酸反应合成。[M(Salen/Salophen/Saldeta/Salpy)-3,5-dicarboxyanilinophenyl-glyoxime)] (7–14) 或 [M(Salen/Salophen)-4-carboxyphenylhydrazinophenylglyoxime)] (15–22) 已从 ( 5) 或 (6) 和信用证。新的异三核和五核配合物（23-38）已从（7-22）和镍（II）盐中获得。然后，合成了异核和 BF2+ 封端的vic-二肟配合物（39-54）。该配合物已被表征为低自旋