[(μ-Cl)₂Sn₂(p-smab)₂Cl₄] | 1459155-23-7

• 英文名称: [(μ-Cl)₂Sn₂(p-smab)₂Cl₄]
• CAS: 1459155-23-7
• 化学式: C₂₈H₂₄Cl₆N₂O₂Sn₂
• 分子量: 870.649
• InChiKey: RKHDNWJGZOTYOI-TYCHDTSASA-F

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  四氢呋喃 、 [(μ-Cl)₂Sn₂(p-smab)₂Cl₄] 反应 48.0h， 以88%的产率得到[(p-smab)SnCl₃·THF]
  参考文献：
  名称：

  Dimeric and monomeric six-coordinate tin(IV) complexes: synthesis and spectral (IR, NMR (¹H, ¹³C, ¹¹⁹Sn), TOF-MS, and ESI-MS) studies

  摘要：

  Six-coordinate dimeric tin(IV) complexes, [(-Cl)(2)Sn-2((2)-sb)(2)Cl-4] {where sb=salicylidene-2-methyl-1-aminobenzene (o-smabH) (1), salicylidene-4-methyl-1-aminobenzene (p-smabH) (2), and salicylidene-2-aminopyridine (sapH) (3)}, have been synthesized by interactions of tin(IV) chloride with the appropriate sodium salt of Schiff bases in 1:1M ratio in isopropanol-benzene. These complexes have been characterized by elemental (C, H, N, and Sn) and spectral [IR, NMR (H-1, C-13, Sn-119), TOF-MS, and ESI-MS] studies. Complexes 1-3 on treatment with an excess of THF afford mononuclear six-coordinate tin(IV) complexes, [(sb)SnCl3THF], 4-6. The biological activities (e.g. antimicrobial action) of the synthesized Schiff bases and 1-3 were assessed by in vitro testing on the growth of various strains of bacteria and fungi.

  DOI：

  10.1080/00958972.2013.800975
• 作为产物：
  描述：

  salicylidene-4-methyl-1-aminobenzene sodium salt 、 四氯化锡 以 异丙醇 、 苯 为溶剂， 反应 5.0h， 以73%的产率得到[(μ-Cl)₂Sn₂(p-smab)₂Cl₄]
  参考文献：
  名称：

  Dimeric and monomeric six-coordinate tin(IV) complexes: synthesis and spectral (IR, NMR (¹H, ¹³C, ¹¹⁹Sn), TOF-MS, and ESI-MS) studies

  摘要：

  Six-coordinate dimeric tin(IV) complexes, [(-Cl)(2)Sn-2((2)-sb)(2)Cl-4] {where sb=salicylidene-2-methyl-1-aminobenzene (o-smabH) (1), salicylidene-4-methyl-1-aminobenzene (p-smabH) (2), and salicylidene-2-aminopyridine (sapH) (3)}, have been synthesized by interactions of tin(IV) chloride with the appropriate sodium salt of Schiff bases in 1:1M ratio in isopropanol-benzene. These complexes have been characterized by elemental (C, H, N, and Sn) and spectral [IR, NMR (H-1, C-13, Sn-119), TOF-MS, and ESI-MS] studies. Complexes 1-3 on treatment with an excess of THF afford mononuclear six-coordinate tin(IV) complexes, [(sb)SnCl3THF], 4-6. The biological activities (e.g. antimicrobial action) of the synthesized Schiff bases and 1-3 were assessed by in vitro testing on the growth of various strains of bacteria and fungi.

  DOI：

  10.1080/00958972.2013.800975