[(4-fluorophenyl)Pd(μ-Cl)2Pd((phenyl)2nacnac)]2 | 1356928-51-2

• 英文名称: [(4-fluorophenyl)Pd(μ-Cl)2Pd((phenyl)2nacnac)]2
• 英文别名: [(4-FPh)Pd)(μ-Cl)2Pd(Ph2nacnac)]2
• CAS: 1356928-51-2
• 化学式: C₄₆H₄₂Cl₄F₂N₄Pd₄
• 分子量: 1256.36
• InChiKey: WZQASNBMQODZBD-MDQSRWMXSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [Pd((phenyl)2nacnac)(pyridine)Cl] 以 氘代苯 、 丙酮 、 苯 为溶剂， 生成 [(4-fluorophenyl)Pd(μ-Cl)2Pd((phenyl)2nacnac)]2
  参考文献：
  名称：

  Palladium β-diiminate chemistry: Reactivity towards monodentate ligands and arylboronic acids

  摘要：

  Here we report the synthesis and characterization of a series of palladium beta-diiminate complexes. Chloro-bridged dimers [Pd(Ar(2)nacnac)(mu-Cl)](2) (where [Ar(2)nacnac] is [(ArNC(CH3))(2)CH] with Ar being aryl substituents) can serve as versatile starting materials, and can be cleaved by neutral monodentate ligands (L) to form mononuclear complexes [Pd(Ar(2)nacnac)(L)Cl], or engage in unusual transmetallation reactions with boronic acids to form tetrapallada-macrocycles. The reactivity of the tetrapallada-macrocyclic complexes towards L-type ligands, as well as the reactivity of Pd(Ar(2)nacnac)(L)Cl] complexes towards boronic acids was also also explored. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.09.044