RuBr2(AsPh3)2(2-[(2,6-diisopropylphenylimino)methyl] phenol) | 1555796-06-9

• 英文名称: RuBr2(AsPh3)2(2-[(2,6-diisopropylphenylimino)methyl] phenol)
• 英文别名: RuBr2(AsPh3)2(DPMP)
• CAS: 1555796-06-9
• 化学式: C₅₅H₅₂As₂Br₂NORu
• 分子量: 1153.75
• InChiKey: OFVUPKFHIPGTHJ-QLUNTVNFSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  水杨醛 以 乙醇 、 苯 为溶剂， 反应 3.0h， 生成 RuBr2(AsPh3)2(2-[(2,6-diisopropylphenylimino)methyl] phenol)
  参考文献：
  名称：

  Synthesis, spectral, electrochemical and catalytic properties of Ru(III) Schiff base complexes containing N, O donors

  摘要：

  A series of new hexa coordinated ruthenium(III) complexes of the type [RuY2(EPh3)(2)(X-DPMP)] (where Y = Br or Cl; E = P or As; DPMP = 2-[(2,6-Diisopropyl-phenylimino)-methyl]-phenol, X = H, Br, Cl, I and Ph) have been synthesized by equimolar [RuY3(EPh3)(3)] and the Schiff base ligands in benzene. The bidentate Schiff base ligands (X-DPMP) have been derived from condensation of 2,6-diisopropylaniline with mono and multisubstituted salicylaldehyde derivatives. The complexes have been characterized by elemental analysis, magnetic susceptibility, UV-Vis., IR and EPR spectral and electrochemical measurements. All the ruthenium(III) complexes are found to be stable, paramagnetic, low spin, redox active and display either quasi reversible or irreversible redox couples based on metal centre. They have exhibited catalytic activity for the oxidation of wide range of primary and secondary alcohols to corresponding aldehydes or ketones with moderate to high conversion in the presence of N-methylmorpholine-N-oxide (NMO) as co-oxidant. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2013.12.048