[(1,1,1-tris(diphenylphosphinomethyl)ethane)Co(III)(η3-crotyl)(CN)][PF6] | 904285-63-8

• 英文名称: [(1,1,1-tris(diphenylphosphinomethyl)ethane)Co(III)(η3-crotyl)(CN)][PF6]
• CAS: 904285-63-8
• 化学式: CN*C₄₅H₄₆CoP₃*F₆P
• 分子量: 909.757
• InChiKey: KMJZXNYKNYANPA-COMVAPIWSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [(1,1,1-tris(diphenylphosphinomethyl)ethane)Co(III)(η3-crotyl)(CN)][PF6] 以 not given 为溶剂， 以100%的产率得到1,1,1-tris(diphenylphosphinomethyl)ethane cobalt hexafluorophosphate
  参考文献：
  名称：

  Reactivity of 2-methyl-3-butenenitrile in the presence of catalytic amounts of various cobalt complexes in ionic liquid

  摘要：

  The behavior of 2-methyl-3-butenenitrile (2M3BN) in the presence of catalytic amount of several cobalt complexes was evaluated. Irrespective of the nature of cobalt complexes and the experimental conditions (presence of ligand [such as P(OPh)(3) or pyridine], or/and of Lewis acid [ZnCl2, AlCl3], organic solvent or ionic liquid), the product of isomerization 2-methyl-2-butenenitrile was obtained instead of the expected rearranged product 3-pentenenitrile (3PN). This result was explained by the activation of C-H bond instead of C-CN bond. With 3PN, the first example of a reversible cleavage of the C-CN with complex derived from Co+ was evidenced. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2005.11.006
• 作为产物：
  描述：

  thallium(I) hexafluorophosphate 、 [1,1,1,-tris((diphenylphosphino)methyl)ethane]cobalt(I) chloride 、 3-戊烯腈 以 四氢呋喃 为溶剂， 以50%的产率得到[(1,1,1-tris(diphenylphosphinomethyl)ethane)Co(III)(η3-crotyl)(CN)][PF6]
  参考文献：
  名称：

  Reactivity of 2-methyl-3-butenenitrile in the presence of catalytic amounts of various cobalt complexes in ionic liquid

  摘要：

  The behavior of 2-methyl-3-butenenitrile (2M3BN) in the presence of catalytic amount of several cobalt complexes was evaluated. Irrespective of the nature of cobalt complexes and the experimental conditions (presence of ligand [such as P(OPh)(3) or pyridine], or/and of Lewis acid [ZnCl2, AlCl3], organic solvent or ionic liquid), the product of isomerization 2-methyl-2-butenenitrile was obtained instead of the expected rearranged product 3-pentenenitrile (3PN). This result was explained by the activation of C-H bond instead of C-CN bond. With 3PN, the first example of a reversible cleavage of the C-CN with complex derived from Co+ was evidenced. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2005.11.006