1,2-C2B10H11-9(or 12)-COCl | 61653-92-7

• 英文名称: 1,2-C2B10H11-9(or 12)-COCl
• CAS: 61653-92-7
• 化学式: C₃H₁₁B₁₀ClO
• 分子量: 206.683
• InChiKey: XCVFIFDDSWZCFH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  1,2-C2B10H11-9(or 12)-COCl 在 lithium aluminium tetrahydride 作用下， 以 乙醚 为溶剂， 以82%的产率得到9-(hydroxymethyl)-1,2-dicarba-closo-dodecaborane
  参考文献：
  名称：

  Synthesis of some functional derivatives ofo- andm-carboranes

  摘要：

  Amides, amines, and alcohols were synthesized from 9-o- and 9-m-carboranecarboxylic chlorides. It follows from comparison of the H-1 NMR spectra of N,N-dimethyl-1-o- and -1-m-carboranecarboxamides and N,N-dimethyl-9-o- and -9-m-carboranecarboxamides that pi-bonding of the carborane polyhedron with the carbonyl group in 1-carboranyl dimethylamides is stronger than that in 9-carboranyl diethylamides. Oxidation of 9-hydroxymethyl-m-carborane with pyridinium chlorochromate gives 9-m-carboranylmethyl 9-m-carboranecarboxylate.

  DOI：

  10.1007/bf01435805
• 作为产物：
  描述：

  氯化亚砜 、 o-carborane-9-carboxylic acid 生成 1,2-C2B10H11-9(or 12)-COCl
  参考文献：
  名称：

  Mironov, V. F.; Pechurina, S. Ya.; Grigos, V. I., Doklady Akademii nauk SSSR, 1976, vol. 226/231, p. 619 - 622

  摘要：

  DOI：

文献信息

• Ferrocenyl substituted oxo-derivatives of carboranes: Synthesis and some chemical transformations
  作者：Valentina A. Ol’shevskaya、Maria D. Kotova、Elena G. Kononova、Alexander S. Peregudov、Valery N. Kalinin

  DOI：10.1016/j.poly.2014.08.015

  日期：2015.1

  Abstract Friedel-Crafts acylation reaction of ferrocene with carborane carboxylic acid chlorides was shown to be a facile and convenient route for the preparation of carboranyl ferrocenyl oxo-derivatives in high yield. Compounds thus obtained were easily transformed into the corresponding alcohols using lithium aluminum hydride whereas their conversion into the corresponding ferrocenylalkyl carboranes

  摘要二茂铁与碳硼烷羧酸氯化物的Friedel-Crafts酰化反应被证明是一种高产率地制备碳硼烷基二茂铁氧代衍生物的简便方法。使用氢化锂铝将如此获得的化合物容易地转化为相应的醇，而用一氯铝烷将其转化为相应的二茂铁基烷基碳硼烷。在CAN催化下，研究了S-亲核试剂取代碳硼烷基二茂铁基醇中的羟基。
• Use of carborane carboxylic acids in the synthesis of boronated nitrogen heterocycles
  作者：Valentina A. Ol’shevskaya、Anton V. Makarenkov、Elena G. Kononova、Pavel V. Petrovskii、Mikhail S. Grigoriev、Valery N. Kalinin

  DOI：10.1016/j.poly.2012.12.035

  日期：2013.3

  of 5-substituted carborane tetrazoles was synthesized by acylation of 5-phenyl-1-H-tetrazole with the available o- and m-carborane carboxylic acid chlorides or o- and m-carborane acetic acid chlorides in the presence of pyridine. Successive thermolysis of the carborane tetrazoles in toluene followed by the extrusion of nitrogen resulted in a series of previously unknown carborane 1,3,4-oxadiazoles

  一种新型系列5-取代的碳硼烷四唑，通过用现有的5-苯基-1-H-四唑的合成酰化ø -和中号-carborane羧酸氯化物或ö和-中号在吡啶的存在下-carborane乙酸氯化物。甲硼烷四唑在甲苯中的连续热解，然后挤出氮气，以高收率得到了一系列先前未知的甲硼烷1,3,4-恶二唑。以2,4-二氯苯胺为例，我们表明碳硼烷取代的1,3,4-恶二唑可转化为相应的1,2,4-三唑。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: B: B Comp.SVol.1/3, 13.18.3.2, page 213 - 227
  作者：

  DOI：——

  日期：——
• Synthesis of 9-pentacarbonylrhenium-m-carborane from 9-m-carboranecarbonyl chloride
  作者：L. I. Zakharkin、V. A. Ol'shevskaya

  DOI：10.1007/bf01557529

  日期：1987.7