| 338963-74-9

• CAS: 338963-74-9
• 化学式: BF₄*C₄₅H₃₈NOP₂Pd
• 分子量: 863.975
• InChiKey: WCLFTQNVMHLPGW-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  、 一氧化碳 以 二氯甲烷 为溶剂， 以75%的产率得到
  参考文献：
  名称：

  Reddy, K. Rajender; Tsai, Wei-Wen; Surekha, Journal of the Chemical Society. Dalton Transactions (2001), 2002, # 8, p. 1776 - 1782

  摘要：

  DOI：

文献信息

• Study of Insertion of Olefins and/or Carbon Monoxide into Phosphine−Imine Palladium Methyl Complexes
  作者：K. Rajender Reddy、K. Surekha、Gene-Hsiang Lee、Shie-Ming Peng、Jwu-Ting Chen、Shiuh-Tzung Liu

  DOI：10.1021/om000880q

  日期：2001.4.1

  Palladium methyl complexes with a phosphine-imine (P similar toN) bidentate ligand, [Pd(P similar toN)-MeCl] (1), [Pd(P similar toN)Me(CH3CN)] (BF4) (2), and [Pd(P similar toN)Me(PPh3)] (BF4) (3), are treated with CO to result in the corresponding Pd-acyl complexes 4-6. NMR studies indicate the formation of a sole isomer with the acyl group cis to the phosphine donor. The neutral complex 4 and the triphenylphosphine-substituted complex 6 cannot serve for the insertion of ethylene. However, the acetonitrile complex 5 appears to be active in the insertion reaction with various alkenes as well as ethylene/CO (E-CO) co-oligomerization, resulting in the products 7-14 and 16, which have been isolated and characterized by spectroscopic methods. X-ray structures of 1, 2, 3, 4, 7, 10, 11, and 13 are revealed.