[(η5-C5Me5)WCl2(μ-H)]2 | 313474-64-5

• 英文名称: [(η5-C5Me5)WCl2(μ-H)]2
• CAS: 313474-64-5
• 化学式: C₂₀H₃₂Cl₄W₂
• 分子量: 781.986
• InChiKey: IIVSYOPRGNRCIH-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [(η5-C5Me5)WCl2(μ-H)]2 以 氘代甲苯 为溶剂， 生成 氢气
  参考文献：
  名称：

  Synthesis and structure of [(η5-C5Me5)WCl2(μ-H)]2. A dinuclear tungsten hydride with a double bond formed from the reaction of BH3THF with (η5-C5Me5)WCl4

  摘要：

  The reaction of limited quantities of BH3THF with Cp*WCl4, Cp* = eta(5)-C5Me5, leads to the formation of [Cp*WCl2(mu-H)12 and BH2Cl in good yield. Structural characterization by spectroscopic and crystallographic techniques reveals the presence of two Cp*WCl2 fragments in a transoid arrangement connected by a formal W=W double bond (d(ww) = 2.5150(5) Angstrom) bridged by two hydrogen atoms. Reaction of [Cp*WCl2(mu-H)](2) with additional BH3THF leads ultimately to Cp-2*W2B5H9, thereby providing information on the role of [Cp*WCl2(mu-H)](2) as an intermediate in the formation of Cp-2*W2B5H9 from the reaction of Cp*WCl4 with an excess of BH,THF. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00084-x
• 作为产物：
  描述：

  tetrachloro(η-pentamethylcyclopentadienyl)tungsten(V) 在 BH₃(C₄H₈O) 作用下， 以 甲苯 为溶剂， 以80%的产率得到[(η5-C5Me5)WCl2(μ-H)]2
  参考文献：
  名称：

  Synthesis and structure of [(η5-C5Me5)WCl2(μ-H)]2. A dinuclear tungsten hydride with a double bond formed from the reaction of BH3THF with (η5-C5Me5)WCl4

  摘要：

  The reaction of limited quantities of BH3THF with Cp*WCl4, Cp* = eta(5)-C5Me5, leads to the formation of [Cp*WCl2(mu-H)12 and BH2Cl in good yield. Structural characterization by spectroscopic and crystallographic techniques reveals the presence of two Cp*WCl2 fragments in a transoid arrangement connected by a formal W=W double bond (d(ww) = 2.5150(5) Angstrom) bridged by two hydrogen atoms. Reaction of [Cp*WCl2(mu-H)](2) with additional BH3THF leads ultimately to Cp-2*W2B5H9, thereby providing information on the role of [Cp*WCl2(mu-H)](2) as an intermediate in the formation of Cp-2*W2B5H9 from the reaction of Cp*WCl4 with an excess of BH,THF. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00084-x