1,1,1-triphenyl-N-(triphenyl-l5-phosphaneylidene)-l5-phosphaniminium hexaazidophosphate(V) | 1089734-59-7

• 英文名称: 1,1,1-triphenyl-N-(triphenyl-l5-phosphaneylidene)-l5-phosphaniminium hexaazidophosphate(V)
• CAS: 1089734-59-7
• 化学式: C₃₆H₃₀NP₂*N₁₈P
• 分子量: 821.683
• InChiKey: ZPSCSYJYFHPOGH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  、 bis(triphenylphosphoranylidene)ammonium azide 以 乙腈 为溶剂， 以76%的产率得到1,1,1-triphenyl-N-(triphenyl-l5-phosphaneylidene)-l5-phosphaniminium hexaazidophosphate(V)
  参考文献：
  名称：

  Experimental and Theoretical Characterization of the Hexaazidophosphate(V) Ion

  摘要：

  (PPN)[P(N(3))(6)] (2) was synthesized by the metathesis of Na[P(N(3))(6)] (1) and (PPN)N(3) (PPN(+) = {(Ph(3)P)(2)N}(+)), allowing for the isolation and full characterization of a stable hexaazidophosphate(V) salt by (31)P and (14)N NMR, UV absorption, IR and Raman spectroscopy, elemental and thermal analyses, X-ray diffraction, and Hartree-Fock and density functional theory calculations. The colorless single crystals of 2 are triclinic, space group P1, a = 9.6296(9), b = 9.8158(9), c = 10.1414(10) angstrom, alpha = 92.635(5)degrees, beta = 93.437(5)degrees, gamma = 92.105(4)degrees, and Z = 1. The [P(N(3))(6)](-) ion of 2 is isolated in the solid state and adopts S(6) symmetry both in the crystal and in solution. Thermogravimetric analysis and differential scanning calorimetry measurements reveal a surprising thermal stability of 2 (T(dec) ca. 200 degrees C). No friction sensitivity was encountered.

  DOI：

  10.1021/ic801536z