mer-[RuCl(CNPh)3(Ph2PCH2PPh2)]Cl | 163087-53-4

• 英文名称: mer-[RuCl(CNPh)3(Ph2PCH2PPh2)]Cl
• CAS: 163087-53-4
• 化学式: C₄₆H₃₇ClN₃P₂Ru*Cl
• 分子量: 865.743
• InChiKey: ORNOGYUXFDOEFQ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  trans-dichlorotetra(phenylisocyanide)ruthenium(II) 、 双二苯基膦甲烷 以 甲苯 为溶剂， 以42.5%的产率得到cis,cis,trans-[RuCl2(CNPh)2(Ph2PCH2PPh2-P)2]
  参考文献：
  名称：

  New mixed-ligand isocyanide diphosphine ruthenium(II) derivatives. Synthesis of a potential metal-containing tetradentate ligand

  摘要：

  Reaction of trans-[RuCl2(CNPh)(4)] with an excess of Ph(2)PCH(2)PPh(2) (dppm) in refluxing toluene gave two complexes cis,cis,trans-[RUCl(2)(CNPh)(2)(dppm-P)(2)] 1 and mer- [RuCl(CNPh)(3)(dppm)]Cl 2a; whereas in the reaction of trans-[RuCl2(CNBu(t))(4)] with dppm under the same conditions only mer-[RuCl-(CNBu(t))(3)(dppm)]Cl 2b was obtained. Complex 1 reacted with TlPF6 in CH2Cl2 to give [RuCl(CNPh)(2)(dppm) (dppm-P)]PF6 3, a cationic complex containing both a monodentate and a chelated dppm ligand. Complex 1 is remarkable in having two monohapto dppm ligands and can be used in the synthesis of heterometallic species. Thus, treatment of 1 with AgClO4 or HgCl2 gave the heterometallic complex [(dppm)(PhNC)(2)ClRu(mu-dppm)AgCl]ClO4 4 or [{(dppm)(PhNC)(2)ClRu-(mu-dppm)HgCl2}(2)] Cl-2 5 respectively.

  DOI：

  10.1039/dt9950001069