[(η5-C5Me5)Ir(CO)(μ2-cyanamido(2-)-N,N)(μ2-cyanogen isocyanate)Ir(η5-C5Me5)] | 852509-49-0

• 英文名称: [(η5-C5Me5)Ir(CO)(μ2-cyanamido(2-)-N,N)(μ2-cyanogen isocyanate)Ir(η5-C5Me5)]
• CAS: 852509-49-0
• 化学式: C₂₄H₃₀Ir₂N₄O₂
• 分子量: 790.968
• InChiKey: UGNYFVYCLVHZQA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [Cp*Ir(μ2-NCN-N,N)]2 、 一氧化碳 以 not given 为溶剂， 以82%的产率得到[(η5-C5Me5)Ir(CO)(μ2-cyanamido(2-)-N,N)(μ2-cyanogen isocyanate)Ir(η5-C5Me5)]
  参考文献：
  名称：

  A Cyanamido-Bridged Diiridium Complex:  A Reactive Building Block for Polynuclear Cyanamido Complexes

  摘要：

  [Cp*IrCl2](2) reacts with 2 equiv of Na2NCN to afford the NCN-bridged diiridium complex [Cp*Ir(mu(2)-NCN-N,N)](2) (5), which undergoes further reactions with donor molecules such as CO and phosphines. Complex 5 works as an excellent building block for the synthesis of the NCN-capped heterotrinuclear complexes [(Cp*Ir)(2)(ML)(mu(3)-NCN-N,N,N)(2)](+) (ML = Rh(cod), CpRu, Pd(eta(3)-C3H5)) on reactions with cationic group 8-10 metal complexes such as [Rh(cod)(acetone)](+), [CpRu(MeCN)(3)](+), and [Pd(eta(3)-C3H5)(acetone)(n)](+), while the dimerization of 5 leads to the cubane-type tetrairidium complex [Cp*Ir(mu(3)-NCN-N,N,N)](4).

  DOI：

  10.1021/om048978i