[MnCl2(1,3-bis(6-methylpyridin-2-yl)pyridine)] | 1286686-69-8

• 英文名称: [MnCl2(1,3-bis(6-methylpyridin-2-yl)pyridine)]
• CAS: 1286686-69-8
• 化学式: C₁₇H₁₅Cl₂MnN₃
• 分子量: 387.17
• InChiKey: CLIAINXMFMVTER-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2,6-双(6-甲基吡啶-2-基)吡啶 、 manganese(ll) chloride 以 二氯甲烷 、 乙腈 为溶剂， 以69.3%的产率得到[MnCl2(1,3-bis(6-methylpyridin-2-yl)pyridine)]
  参考文献：
  名称：

  New mononuclear manganese(II) and zinc(II) complexes with a terpyridine ligand: Structural, magnetic and spectroscopic properties

  摘要：

  Six mononuclear complexes of the dimethylterpyridine ligand 1,3-bis(6-methylpyridin-2-yl)pyridine, L, C17H15N3, of the general formula MLX2 were prepared from different manganese(II) and zinc(II) salts (M = Mn(II), X = Cl- - 1a, Br- - 1b, NO3- - 1c and ClO4- - 1d; M = Zn(II), X = Cl- - 2a and NO3- - 2c). The complexes have been characterized through analytical, spectroscopic (UV-Vis, ESI-MS, and IR) and magnetic measurements. Single crystal X-ray structure analyses of these complexes revealed five-coordinate metal ions in 1a, 1c, 2a and 2c, whereas 1d turned out to contain a six-coordinate Mn(II) ion. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.12.032