[(η6-1-Me-4-i-Pr-C6H4)RuCl2(PH2(η5-C5H4)Fe(η5-C5H5))] | 851867-78-2

• 英文名称: [(η6-1-Me-4-i-Pr-C6H4)RuCl2(PH2(η5-C5H4)Fe(η5-C5H5))]
• 英文别名: [(η6-p-cymene)RuCl2(PH2(η5-C5H4)Fe(η5-C5H5))]
• CAS: 851867-78-2
• 化学式: C₂₀H₂₅Cl₂FePRu
• 分子量: 524.215
• InChiKey: DLUMIKOIMVUJGA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 、 膦二茂铁 以 四氢呋喃 为溶剂， 以94%的产率得到[(η6-1-Me-4-i-Pr-C6H4)RuCl2(PH2(η5-C5H4)Fe(η5-C5H5))]
  参考文献：
  名称：

  Molecular structures of ruthenium half-sandwich complexes with primary and secondary phosphines: [(η6-p-cymene)RuCl2(PR3)] [p-cymene=1-Me-4-PriC6H4; PR3=PH2Fc, PH2CH2Fc, PH(CH2Fc)2; Fc=Fe(η5-C5H4)(η5-C5H5)]

  摘要：

  A series of air-stable half-sandwich complexes of general formula[(eta(6) -p-cymene)RuCl2(PR3)] [p-cymene = 1-Me-4-Pr'C6H4; PR3 = PH(2)Fc (1), PH(CH(2)Fc)(2) (3); Fc = Fe(eta(5) -C5H4)(eta(5)-(CH5)-H-5)] were synthesized from [{(p-cymene)RuCl2}(2)] and the corresponding phosphine and fully characterized by IR and NMR (H-1, C-13, (31)p) spectroscopy. Molecular structures of [(eta(6)-p-cymene)RuCl2(PR3)] [PR3 = PH(2)Fc (1), PH2CH2Fe (2), PH(CH(2)Fc)(2) (3)] are reported. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.02.006