PtCl[C6H4-CH=N-(C6H4-2-S(methyl))](triphenylphosphine) | 554449-57-9

• 英文名称: PtCl[C6H4-CH=N-(C6H4-2-S(methyl))](triphenylphosphine)
• CAS: 554449-57-9
• 化学式: C₃₂H₂₇ClNPPtS
• 分子量: 719.146
• InChiKey: OLNNINKJCIYMHV-DQAXRLSZSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  benzylidene-(2-methylsulfanyl-phenyl)-amine 以 二氯甲烷 、 甲苯 为溶剂， 生成 PtCl[C6H4-CH=N-(C6H4-2-S(methyl))](triphenylphosphine)
  参考文献：
  名称：

  Synthesis, characterisation and study of the first luminescent platinum(II) compound with a [C,N,S]− terdentate ligand. X-ray crystal structure of [Pt{C6H4CHN(C6H42-SMe)}Cl]

  摘要：

  The study of the reactions of the thioimine C6H5-CH=N-(C6H4-2-SMe) with cis-[PtCl2DMSO)(2)] or cis-[PtCl2(PhCN)(2)] is reported. The results obtained from the reactions of cis-[PtCl2(DMSO)(2)] with the Schiff base suggest that this platinum(II) complex induces the hydrolyses of the imine. In contrast to these findings, the treatment of equimolar amounts of C6H5-CH=N-(C6H4-2- SMe) and cis-[PtCl2(PhCN)(2)] under refluxing toluene lead to the cycloplatinated complex: [Pt{C6H4-CH=N-(C6H4-2-SMe)}Cl], which is luminescent in solution at 298 K. The X-ray crystal structure of this compound reveals that the ligand acts as a [C(sp(2)),N,S](-) ligand and has the E (anti-) conformation. The reaction of the cycloplatinated compound [Pt{C6H4-CH=N-(C6H4-2-SMe)}Cl] with PPh3 is also reported. This process produces the cleavage of the Pt-S bond and the formation of [Pt{C6H4-CH=N-(C6H4-2-SMe) Cl(PPh3)] in which the ligand acts as a monoanionic (C,N)(-) bidentate group. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(03)00011-1