N-(6-aminopyridin-2-yl)ferrocene | 154292-79-2

• 英文名称: N-(6-aminopyridin-2-yl)ferrocene
• CAS: 154292-79-2
• 化学式: C₁₆H₁₅FeN₃O
• 分子量: 321.162
• InChiKey: KADCJBIKKVNNKE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,6-二氨基吡啶 、 二茂铁甲酸 在 三乙胺 、 N-[(dimethylamino)-3-oxo-1H-1,2,3-triazolo[4,5-b]pyridin-1-yl-methylene]-N-methylmethanaminium hexafluorophosphate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 13.0h， 生成 N-(6-aminopyridin-2-yl)ferrocene
  参考文献：
  名称：

  In vivo monitoring of local pH values in a live rat brain based on the design of a specific electroactive molecule for H⁺

  摘要：

  我们已经开发出了一种双通道电化学比率生物传感器，用于在大鼠不同脑区进行局部pH值测定，具有显著的选择性和准确性，并报告了准确的pH值。

  DOI：

  10.1039/c5cc09540a

文献信息

• Selective electrochemical recognition of the dihydrogen phosphate anion in the presence of hydrogen sulfate and chloride ions by new neutral ferrocene anion receptors
  作者：Paul D. Beer、Zheng Chen、Alistair J. Goulden、Andrew Graydon、Sally E. Stokes、Trevor Wear

  DOI：10.1039/c39930001834

  日期：——

  New neutral ferrocene anion receptors L3, L4, L5 selectively complex, electrochemically recognise and respond to the dihydrogen phosphate guest anion in the presence of excess amounts of hydrogen sulfate and chloride anions.

  在存在过量的硫酸氢根和氯离子的情况下，新的中性二茂铁阴离子受体L 3，L 4，L 5选择性地络合，电化学识别并响应磷酸二氢客体阴离子。
• Electrochemical response to anions in acetonitrile by neutral molecular receptors containing ferrocene, amide and amine moieties
  作者：Zheng Chen、Andrew R. Graydon、Paul D. Beer

  DOI：10.1039/ft9969200097

  日期：——

  Voltammetric and NMR investigations of anion binding by neutral ferrocene-based receptors have been performed in aprotic environments. NMR studies show that the amide functionalised ligands are capable of interaction with a variety of anions, including chloride, hydrogensulfate and dihydrogenphosphate anions. Stability constants were elucidated where possible. Electrochemical studies highlight a characteristic

  已在非质子环境中进行了中性二茂铁基受体与阴离子结合的伏安法和NMR研究。NMR研究表明，酰胺官能化的配体能够与多种阴离子相互作用，包括氯离子，硫酸氢根和磷酸二氢根阴离子。在可能的情况下阐明稳定性常数。电化学研究突出了在磷酸二氢根阴离子存在下二茂铁的特征行为。另外，观察到官能化受体对阴离子的电化学识别。参照所提出的结合位点上可用的官能团来合理化选择性的趋势。
• Second harmonic generation in ferrocene based hydrogen bonded assemblies
  作者：Sushanta K Pal、Anu Krishnan、Puspendu K Das、Ashoka G Samuelson

  DOI：10.1016/s0022-328x(01)00960-3

  日期：2001.12

  Supramolecular assemblies formed by electron donors and acceptors might possess very large optical nonlinearity, even larger than the sum of the constituents if they form noncentrosymmetric networks. To probe this hypothesis we have functionalized barbituric acid, by condensing it with ferrocene carboxaldehyde to give 1, a hydrogen bond donor-acceptor-donor (H-DAD). This molecule complements the hydrogen bond donor acceptor sites of 2,6-diaminopyridine (2) which is a hydrogen bond acceptor-donor-acceptor (H-ADA). 2,6-Diaminopyridine was further functionalized with acetyl ferrocene to give 3, which forms complexes with 1. Complex formation was studied using nuclear magnetic resonance spectroscopy. The second order nonlinear optical (NLO) response of these hydrogen bonded assemblies has been probed by hyper Rayleigh scattering (HRS) measurements and was found to be maximum when I was mixed with five equivalents of 3. A plausible explanation for the formation of 1:5 complex was given on the basis of control experiments with 4, a methylated analog of 1, and the addition of a strong hydrogen bond acceptor solvent, methanol. (C) 2001 Elsevier Science B.V. All rights reserved.