[Pt(PhNC(O)CH(COPh))(cyclo-octa-1,5-diene)] | 247577-16-8

• 英文名称: [Pt(PhNC(O)CH(COPh))(cyclo-octa-1,5-diene)]
• CAS: 247577-16-8
• 化学式: C₂₃H₂₃NO₂Pt
• 分子量: 540.521
• InChiKey: UXUYDLCUNJOLSI-GHDUESPLSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Pt(PhNC(O)CH(COPh))(cyclo-octa-1,5-diene)] 、 1,2-双(二苯基膦)乙烷 以 二氯甲烷 为溶剂， 以89%的产率得到
  参考文献：
  名称：

  Platina- and palladalactam complexes derived from 2-benzoylacetanilide; syntheses and X-ray structure of [Pd{NPhC(O)CHC(O)Ph}(bipy)]·CH2Cl2

  摘要：

  Reactions of the complexes [PtCl2(cod)] (cod = cyclo-octa-1,5-diene), cis-[PtCl2(PPh3)(2)], and [PdCl2(bipy)] (bipy = 2,2'-bipyridine) with 2-benzoylacetanilide and excess silver(I) oxide gives metallalactam complexes [M{PhNC(O)CH(COPh)}L-2] in good yields. The complexes have been characterised by NMR and IR spectroscopies, elemental analysis, and electrospray mass spectrometry (ESMS). A single-crystal X-ray structure of the bipy palladium complex reveals the expected four-membered ring system, which is almost planar. No evidence was observed for platinum-oxygen bonded products, which were a possibility based on the result of the related system involving PhC(O)CH2C(O)CH2C(O)Ph reported in the literature, which yielded a six-membered dienediolate platinacycle. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00190-5
• 作为产物：
  描述：

  2-苯甲酰乙酰苯胺 、 dichloro( 1,5-cyclooctadiene)platinum(ll) 在 Ag₂O 作用下， 以 二氯甲烷 为溶剂， 以69%的产率得到[Pt(PhNC(O)CH(COPh))(cyclo-octa-1,5-diene)]
  参考文献：
  名称：

  Platina- and palladalactam complexes derived from 2-benzoylacetanilide; syntheses and X-ray structure of [Pd{NPhC(O)CHC(O)Ph}(bipy)]·CH2Cl2

  摘要：

  Reactions of the complexes [PtCl2(cod)] (cod = cyclo-octa-1,5-diene), cis-[PtCl2(PPh3)(2)], and [PdCl2(bipy)] (bipy = 2,2'-bipyridine) with 2-benzoylacetanilide and excess silver(I) oxide gives metallalactam complexes [M{PhNC(O)CH(COPh)}L-2] in good yields. The complexes have been characterised by NMR and IR spectroscopies, elemental analysis, and electrospray mass spectrometry (ESMS). A single-crystal X-ray structure of the bipy palladium complex reveals the expected four-membered ring system, which is almost planar. No evidence was observed for platinum-oxygen bonded products, which were a possibility based on the result of the related system involving PhC(O)CH2C(O)CH2C(O)Ph reported in the literature, which yielded a six-membered dienediolate platinacycle. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00190-5