dichlorido[2-(4,5-dimethyl-1Н-imidazol-2-yl)pyridine]cadmium | 1416621-16-3

• 英文名称: dichlorido[2-(4,5-dimethyl-1Н-imidazol-2-yl)pyridine]cadmium
• 英文别名: Cd[2-(4,5-dimethyl-1H-imidazol-2-yl)pyridine]Cl₂
• CAS: 1416621-16-3
• 化学式: C₁₀H₁₁CdCl₂N₃
• 分子量: 356.533
• InChiKey: UGPVJZWFZDQHLL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  吡啶-2-甲醛 在 ammonium acetate 作用下， 以 甲醇 、 乙醇 为溶剂， 反应 24.5h， 生成 dichlorido[2-(4,5-dimethyl-1Н-imidazol-2-yl)pyridine]cadmium
  参考文献：
  名称：

  Luminescent zinc(II) and cadmium(II) complexes based on 2-(4,5-dimethyl-1H-imidazol-2-yl)pyridine and 2-(1-hydroxy-4,5-dimethyl-1H-imidazol-2-yl)pyridine

  摘要：

  Complexes (ZnLCl2)-Cl-1, (CdLCl2)-Cl-1, ZnL (2) (1) Cl-2 (center dot)1.5H(2)O, CdL (2) (1) Cl-2 (center dot)2H(2)O, CdL (2) (1) Cl-2 (MeOH)-Me-center dot center dot H2O [L-1 = 2-(4,5-dimethyl-1H-imidazol-2-yl)pyridine] and inner-complex compounds ZnL (2) (2) center dot 2H(2)O, CdL (2) (2) [HL2 = 2-(1-hydroxy-4,5-dimethyl-1H-imidazol-2-yl)pyridine] were synthesized. The complexes exhibit bright photoluminescence in the blue region of the spectrum, with the intensity exceeding this characteristic of the compounds L-1 and HL2. Compound L-1 in aqueous solution is a potential chemosensor for the determination of zinc and cadmium.

  DOI：

  10.1134/s1070363212110230