| 1431359-30-6

• CAS: 1431359-30-6
• 化学式: C₃₂H₃₅Cl₂N₅RhZn*Cl
• 分子量: 764.318
• InChiKey: NKOHDQZDWNREJT-XHLHPPAUSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  、 chloro(1,5-cyclooctadiene)rhodium(I) dimer 以 四氢呋喃 为溶剂， 以47%的产率得到
  参考文献：
  名称：

  Evaluation of Multisite Polypyridyl Ligands as Platforms for the Synthesis of Rh/Zn, Rh/Pd, and Rh/Pt Heterometallic Complexes

  摘要：

  Ligands containing linked dipicolylamine (dpa) and bipyridine (bpy) sites have been utilized in the synthesis of monometallic and heterometallic complexes. The two sites have different selectivities for metal binding, which allows preferential formation of singly metalated complexes. The dpa site of the ligands has been observed to bind selectively to Zn2+, Pd2+, and Pt2+, while the bpy site binds selectively to Rh+. Addition of a second metal then results in the formation of heterometallic products. In the presence of CD3OD, the heterometallic Rh/Pt and Rh/Pd complexes undergo rapid selective H/D exchange of one of the diastereotopic protons of the dpa methylene group.

  DOI：

  10.1021/ic301810y