[Mo(CO)5(amsh)] | 796043-48-6

• 英文名称: [Mo(CO)5(amsh)]
• 英文别名: [Mo(CO)5(acetonemethanesulfonylhydrazone)]
• CAS: 796043-48-6
• 化学式: C₉H₁₀MoN₂O₇S
• 分子量: 386.194
• InChiKey: ITJNBMKIPIZMPD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  Acetone methanesulfonylhydrazone 、 molybdenum hexacarbonyl 以 四氢呋喃 为溶剂， 以83%的产率得到[Mo(CO)5(amsh)]
  参考文献：
  名称：

  Synthesis and Characterization of Metal Carbonyl Complexes of M(CO)₆ (M = Cr, Mo, and W), Re(CO)₅Br, and Mn(CO)₃Cp with Acetonemethanesulfonylhydrazone (amsh) and Methanesulfonylhydrazone (msh)

  摘要：

  Ten new complexes, [M(CO)(5)(amsh)] [M = Cr; (1a), Mo; (2a), W; (3a)], [Re(CO)(4)Br(amsh)] (4a), and [Mn(CO)(2)(amsh)Cp] (5a) and [M(CO)(5) (msh)] [M = Cr; (1b); Mo, (2b); W, (3b)], [Re(CO)4Br(msh)], (4b), and [Mn(CO)(3)(msh)], (5b), have been synthesized by the photochemical reaction of the metal carbonyls [M(CO)(6)] (M = Cr, Mo, and W), [Re(CO)(5)Br], and [Mn(CO)(3)Cp] with acetonemethanesulfonylhydrazone (amsh) and methanesulfonyl hydrazine (msh). The complexes have been characterized by elemental analyses, mass spectrometry, FT-IR and H-1 NMR spectroscopy. The spectroscopic studies show that amsh and msh behave as a monodentate ligands coordinating via an imine N donor atom in (1a)-(5a) and a hydrazine N donor atom in (1b)-(5b).

  DOI：

  10.1081/sim-120037527