[(S)-(-)2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]nickel(II) bromide | 464894-05-1

• 英文名称: [(S)-(-)2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]nickel(II) bromide
• CAS: 464894-05-1
• 化学式: C₄₄H₃₂Br₂NiP₂
• 分子量: 841.184
• InChiKey: XILWBLNWQYIWIH-UHFFFAOYSA-L

物化性质

• 熔点：
  250 °C

反应信息

• 作为产物：
  描述：

  (S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl 、 nickel dibromide 以 四氢呋喃 为溶剂， 以88%的产率得到[(S)-(-)2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]nickel(II) bromide
  参考文献：
  名称：

  Preparation, Crystal Structure Analysis, and Catalytic Application of [(S)-BINAP]Ni(COD) and [(S)-BINAP]NiBr₂

  摘要：

  The efficient preparation of [(S)-BINAP]Ni-(COD) (1) and [(S)-BINAP]NiBr2 (2) is reported. X-ray crystal structure analysis of these potential precatalysts provides the first structural insights into the nickel-BINAP system at both the 0 and +2 oxidation states.

  DOI：

  10.1021/om020164j