[(η5-C5Me5)Ru(η6-dibenzothiophene)[[PF6] | 861255-97-2

• 英文名称: [(η5-C5Me5)Ru(η6-dibenzothiophene)[[PF6]
• CAS: 861255-97-2
• 化学式: C₂₂H₂₃RuS*F₆P
• 分子量: 565.525
• InChiKey: WLLYWMYODQVJEA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  六氟磷酸银 、 (η(5)-cyclopentadienyl)dicarbonylchlororuthenium(II) 、 [(η5-C5Me5)Ru(η6-dibenzothiophene)[[PF6] 以 二氯甲烷 为溶剂， 以82%的产率得到[(η5-cyclopentadienyl)Ru(CO)2(μ2-η1(S):η6-dibenzothiophene)Ru(η5-C5Me5)][PF6]2
  参考文献：
  名称：

  Synthetic, Structural, and Kinetic Studies of [CpRu(CO)₂(μ₂-η¹(S):η⁶-DBT)RuCp*][PF₆]₂:  A Dibenzothiophene Bridge between Two Ruthenium Fragments

  摘要：

  The complexes [CpRu(CO)(2)(mu(2)-eta(1)(S):eta(6)-DBT)RuCp'](2+) (Cp' = eta(5)-C5H5 (3), eta(5)-C5Me5 (4)) were synthesized and shown by X-ray crystallography to contain a bridging dibenzothiophene ligand that is coordinated to {CpRu(CO)(2)}(+) through the sulfur atom and to {Cp'Ru}(+) through an arene ring (eta(6)). Kinetic studies of the displacement of the [Cp*Ru(eta(6)-DBT)](+) moiety in 4 by P(OPh)(3) show that the eta(6)-coordinated {Cp*Ru}(+) group weakens the Ru-S bond, as compared to that in [CpRu(CO)(2)(eta(1)(S)-DBT)](+), and greatly increases the rate of DBT dissociation.

  DOI：

  10.1021/om050158y
• 作为产物：
  描述：

  二苯并噻吩 、 tris(acetonitrile)pentamethylcyclopentadienylruthenium(II) hexafluorophosphate 以 1,2-二氯乙烷 为溶剂， 以79%的产率得到[(η5-C5Me5)Ru(η6-dibenzothiophene)[[PF6]
  参考文献：
  名称：

  Synthetic, Structural, and Kinetic Studies of [CpRu(CO)₂(μ₂-η¹(S):η⁶-DBT)RuCp*][PF₆]₂:  A Dibenzothiophene Bridge between Two Ruthenium Fragments

  摘要：

  The complexes [CpRu(CO)(2)(mu(2)-eta(1)(S):eta(6)-DBT)RuCp'](2+) (Cp' = eta(5)-C5H5 (3), eta(5)-C5Me5 (4)) were synthesized and shown by X-ray crystallography to contain a bridging dibenzothiophene ligand that is coordinated to {CpRu(CO)(2)}(+) through the sulfur atom and to {Cp'Ru}(+) through an arene ring (eta(6)). Kinetic studies of the displacement of the [Cp*Ru(eta(6)-DBT)](+) moiety in 4 by P(OPh)(3) show that the eta(6)-coordinated {Cp*Ru}(+) group weakens the Ru-S bond, as compared to that in [CpRu(CO)(2)(eta(1)(S)-DBT)](+), and greatly increases the rate of DBT dissociation.

  DOI：

  10.1021/om050158y