N-(l4-boraneyl)-1,1,1-trimethyl-N-(trimethylsilyl)silanamine | 186796-04-3

• 英文名称: N-(l4-boraneyl)-1,1,1-trimethyl-N-(trimethylsilyl)silanamine
• CAS: 186796-04-3
• 化学式: C₆H₂₂BNSi₂
• 分子量: 175.229
• InChiKey: DUVRFEWKWIIWJI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  N-(l4-boraneyl)-1,1,1-trimethyl-N-(trimethylsilyl)silanamine 以 not given 为溶剂， 生成 N-Trimethylsilyl-borazan
  参考文献：
  名称：

  Reaction of Hexamethyldisilazane with Borane in Tetrahydrofuran

  摘要：

  AbstractHexamethyldisilazane 1 reacts with borane in tetrahydrofuran (THFBH3, 2) first by formation of an adduct (Me3Si)2NHBH3 (3), and then either to the N,N‐bis‐(trimethylsilyl)‐μ‐aminodiborane 5 or to the mixture of 5 and N‐trimethylsilyl‐μ‐aminodiborane(6) 6, depending on the reaction conditions. The compounds 5 and 6 can be quantitatively converted to the N,N′,N″‐tris(trimethylsilyl)borazine 4. Three intermediates can be identified, namely N,N‐bis(trimethylsilyl)borane 7, N,N‐bis(trimethylsilyl)amino(N′‐trimethylsilylamino)borane 8 and N‐trimethylsilylaminoborane‐trimer. All products and intermediates were characterized by multinuclear NMR spectroscopy, and coupling constant 1J(29Si, 15N) were measured from 29Si NMR spectra by using the Hahn‐echo‐extended (HEED) INEPT pulse sequence.

  DOI：

  10.1002/zaac.19966221208
• 作为产物：
  描述：

  硼烷四氢呋喃络合物 、 六甲基二硅氮烷 以 四氢呋喃 为溶剂， 生成 N-(l4-boraneyl)-1,1,1-trimethyl-N-(trimethylsilyl)silanamine
  参考文献：
  名称：

  Reaction of Hexamethyldisilazane with Borane in Tetrahydrofuran

  摘要：

  AbstractHexamethyldisilazane 1 reacts with borane in tetrahydrofuran (THFBH3, 2) first by formation of an adduct (Me3Si)2NHBH3 (3), and then either to the N,N‐bis‐(trimethylsilyl)‐μ‐aminodiborane 5 or to the mixture of 5 and N‐trimethylsilyl‐μ‐aminodiborane(6) 6, depending on the reaction conditions. The compounds 5 and 6 can be quantitatively converted to the N,N′,N″‐tris(trimethylsilyl)borazine 4. Three intermediates can be identified, namely N,N‐bis(trimethylsilyl)borane 7, N,N‐bis(trimethylsilyl)amino(N′‐trimethylsilylamino)borane 8 and N‐trimethylsilylaminoborane‐trimer. All products and intermediates were characterized by multinuclear NMR spectroscopy, and coupling constant 1J(29Si, 15N) were measured from 29Si NMR spectra by using the Hahn‐echo‐extended (HEED) INEPT pulse sequence.

  DOI：

  10.1002/zaac.19966221208